57598-40-0Relevant academic research and scientific papers
The metal-halogen exchange reaction between ortho-substituted aryl halides and Ph2CuLi·LiCN: Scope and applicability for coupling reactions
?etin, Fatma,Bari? ?eno?ul,Gezer, Sibel,Astley, Demet,Astley, Stephen T.
, p. 154 - 157 (2007/10/03)
Metal-halogen exchange between Ph2CuLi · LiCN and ortho-substituted aryl iodides or bromides may be used to conveniently afford substituted metallated aryls which can subsequently undergo reaction with electrophiles.
THE SYNTHESIS OF 1,2,3-TRISUBSTITUTED BENZENES. FURTHER COMMENTS ON BENZYNES DERIVED FROM ARYL OXAZOLINES
Meyers, A. I.,Pansegrau, Paul D.
, p. 4935 - 4938 (2007/10/02)
Further investigation of organolithium addition to the 2,3-benzyne of aryl oxazolines reveals that addition takes place to give the 3-lithio (kinetic) and/or 2-lithio (thermodynamic) products depending on the nature of the organolithium reagent.
