57748-39-7

Upstream product

• 57613-53-3 5,5-dimethyl-1-trimethylsilylcyclohexene 
• 75-36-5 acetyl chloride 
• 17530-69-7 3-chloro-5,5-dimethylcyclohex-2-en-1-one 
• 2979-19-3 3,3-dimethylcyclohexanone 
• 76181-37-8 1,3-dichloro-5,5-dimethylcyclohexene 
• 76181-36-7 1-chloro-3-hydroxy-5,5-dimethylcyclohexene 
• 76181-38-9 1-chloro-5,5-dimethyl-1-cyclohexene 
• 173547-33-6 5,5-Dimethyl-3-(1-nitroethyl)cyclohexanone 
• 4694-17-1 5,5-dimethlycyclohex-2-en-1-one 

Downstream Products

• 25304-14-7 1-(3,3-dimethyl-cyclohexyl)-ethanone 

Relevant academic research and scientific papers

Clemmensen Reduction. XI. Fragmentation Reactions of Some 3-Acetylcycloalkanones

Clemmensen reduction of a series of 3-acetylcycloalkanones yields, as the major product, an acyclic unsaturated ketone, the product of fragmentation.Some normal carbonyl-methylene reduction also occurs.A mechanistic rationale for the fragmentation is advanced.

Friedel-Crafts Reactions of Some Vinyisilanes

Substituted cyclohexenylsilanes (2), (5), (9), and (13) undergo Friedel-Crafts reactions to give substitution products, site-selectively at the carbon atom carrying the trimethylsilyl group. β-Trimethylsilylstyrene (17) similary gives more substitution in Friedel-Crafts reactions with benzoyl chloride and with phenylacetyl chloride than styrene itself.The syntheses of the silanes are reported, and some limitations of the idea identified.