57750-39-7

Upstream product

• 65961-93-5 Bromo-ethylsulfanyl-phenyl-acetonitrile 
• 64781-77-7 4-diazo-5-phenyl-4H-1,2,3-triazole 
• 71-43-2 benzene 

Downstream Products

• 36214-25-2 3,6-diphenyl-4H-[1,2,4]triazin-5-one 
• 80403-30-1 Benzoic acid [1-cyano-1-phenyl-meth-(Z)-ylidene]-hydrazide 

Relevant academic research and scientific papers

THERMOLYSIS AND PHOTOLYSIS OF 4-DIAZO-1,2,3-TRIAZOLES IN BENZENOID SOLVENTS, SYSTEMS WHICH REVEAL DECOMPOSITION OF DIAZO COMPOUNDS TO CARBENES TO DIAZO COMPOUNDS TO CARBENES.

4-Diazo-1,2,3-triazoles thermolyze and photolyze to 4H-1,2,3-triazolylidenes which (1) convert benzenes to 4-phenyl-1,2,3-triazoles or/and (2) isomerize to α-diazonitriles which react carbenically with benzenes by addition, ring-expansion or substitution processes.

Nouvelles voies d'acces aux diaryl-3,6 hydroxy-5 triazines-1,2,4 a partir des nitriles α-thioethers

Ar-C(CN)=N-N=C(CN)-Ar and Ar-C(CN)=N-NH-CO-Ar', easily prepared from the bromoderivates Ar-CBr(SEt)-CN, afford in good yields, by heating in a basic medium, 3,6-diaryl-5 hydroxy-1,2,4-triazines.