57981-16-5

Basic information

• Product Name: Benzenesulfonamide, N-(1-ethenylbutyl)-4-methyl-
• Synonyms: 3-Tosylaminohex-1-en
• CAS NO: 57981-16-5
• Molecular Formula: C13H19NO2S
• Molecular Weight: 253.365
• Mol File: 57981-16-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzenesulfonamide, N-(1-ethenylbutyl)-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonamide, N-(1-ethenylbutyl)-4-methyl-(57981-16-5)
• EPA Substance Registry System: Benzenesulfonamide, N-(1-ethenylbutyl)-4-methyl-(57981-16-5)

Safety Data

• Hazardous Substances Data: 57981-16-5(Hazardous Substances Data)

Upstream product

• 7688-21-3 cis-2-hexene 
• 55962-05-5 [N-(p-tolylsulfonyl)imino]phenyliodinane 
• 4050-45-7 trans-2-hexene 
• 1437784-91-2 (E)-hex-2-en-1-yl tosylcarbamate 
• 592-41-6 1-hexene 
• 941-55-9 4-toluenesulfonyl azide 
• 99726-00-8 hex-1-en-3-amine hydrochloride 
• 98-59-9 p-toluenesulfonyl chloride 
• 869740-08-9 (E)-N-(2-hex-2-enyloxy-1,3-dimethyl-2λ⁵-[1,3,2]diazaphospholidin-2-ylidene)-4-methyl-benzenesulfonamide 
• 869740-09-0 (Z)-N-(2-hex-2-enyloxy-1,3-dimethyl-2λ⁵-[1,3,2]diazaphospholidin-2-ylidene)-4-methyl-benzenesulfonamide 
• 851-06-9 bis(p-toluenesulfonyl) sulfur diimide 

Relevant articles and documents

Regio- And diastereoselective Pd-catalyzed aminochlorocyclization of allylic carbamates: scope, derivatization, and mechanism

The regio- and diastereoselective synthesis of oxazolidinonesviaa Pd-catalyzed vicinal C-N/C-Cl bond-forming reaction from internal alkenes of allylic carbamates is reported. The oxazolidinones are obtained in yields of 44 to 95% with high to excellent diastereoselectivities (from 6?:?1 to >20?:?1 dr) from readily available precursors. This process is scalable, and the products are suitable for the synthesis of useful amino alcohols. A detailed theoretical and experimental mechanistic study was carried out to describe that the reaction proceeds through ananti-aminopalladation of the alkene followed by an oxidative C-Pd(ii) cleavage with retention of the carbon stereochemistry to yield the major diastereomer. The role of Cu(ii) in a C-Cl bond-forming mechanism step has also been proposed.

A New Class of Redox Isomerization of N-Alkylpropargylamines into N-Alkylideneallylamines Catalyzed by a ReBr(CO)5/Amine N-oxide System

Redox isomerization reaction wherein N-alkylpropargylamines are converted into N-alkylideneallylamines in the presence of rhenium(I) complexes as catalysts is described. Among the additives tested, certain pyridine N-oxides and tertiary amine N-oxides wer

ALLYLIC AMINATION OF ALKENES BY TOSYLIMINOIODOBENZENE : MANGANESE PORPHYRINS AS SUITABLE CATALYSTS

Manganese-porphyrins and particularly Mn(TPP)(ClO4) were found to be much better catalysts than iron-porphyrins for allylic N-tosylamination of alkenes by tosyliminoiodobenzene.With the former catalyst, cyclohexene was selectively transformed into 3-tosyl