58002-98-5Relevant academic research and scientific papers
Macro Rings. 49. Use of Transannular Reactions to Add Bridges to Paracyclophane
Truesdale, E.A.,Cram, Donald J.
, p. 3974 - 3981 (2007/10/02)
New transannular reactions were used to introduce additional bridges into paracyclophane (1).With CH2O-HCl, 4-acetylparacyclophane (3) gave (55percent) 4-acetyl-13-(chloromethyl)paracyclophane (4), whose substituents are pseudogem to one an
Cyclophanes, XIII. On the Chemical Behaviour of (1,2,4)Cyclophane
Murad, Abo El-Fetouh El-Sayed,Hopf, Henning
, p. 2358 - 2371 (2007/10/02)
(1,2,4)Cyclophane (10) has been prepared by several routes from dimethylparacyclophane-4,13-dicarboxylate (5) and subjected to the following reactions: pyrolysis in p-diisopropylbenzene and dimethyl maleate (formation of 13 and 16, respectivel
