10029-00-2

Basic information

• Product Name: Dimer ,4-acetyl [2,2] paracyclophane,
• Synonyms: Dimer ,4-acetyl [2,2] paracyclophane,;1-TRICYCLO(8.2.2.2(4,7))HEXADECA-1(13),4,6,10(14),11,15-HEXAEN-5-YL-ETHANONE
• CAS NO: 10029-00-2
• Molecular Formula: C₁₈H₁₈O
• Molecular Weight: 250.33492
• Mol File: 10029-00-2.mol
• Article Data: 11

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Dimer ,4-acetyl [2,2] paracyclophane,(CAS DataBase Reference)
• NIST Chemistry Reference: Dimer ,4-acetyl [2,2] paracyclophane,(10029-00-2)
• EPA Substance Registry System: Dimer ,4-acetyl [2,2] paracyclophane,(10029-00-2)

Safety Data

• Hazardous Substances Data: 10029-00-2(Hazardous Substances Data)

Upstream product

• 74-86-2 acetylene 
• 741707-36-8 5-acetyl[2,2]paracyclophane oxime 
• 1633-22-3 [2.2]Paracyclophan 
• 75-36-5 acetyl chloride 

Downstream Products

• 732-66-1 (R,S)-methyl-<<2,2>-para-cyclophan-4-yl>carbinol 
• 159184-33-5 1-phenyl-2-(<2.2>-para-cyclophan-4-oyl)ethylene 
• 1436383-41-3 C₂₅H₂₅NO 
• 58002-98-5 1,2,4-<2.2.2>Paracyclophan 
• 24262-07-5 4-methyl<2.2>paracyclophane 
• 74498-50-3 C₁₈H₁₈S 
• 144969-85-7 5-Methyl-1-phenyl-3-tricyclo[8.2.2.2^4,7]hexadeca-1⁽¹³⁾,4,6,10⁽¹⁴⁾,11,15-hexaen-5-yl-1H-pyrazole 
• 199608-34-9 (1-Methyl-1-tricyclo[8.2.2.2^4,7]hexadeca-1⁽¹³⁾,4,6,10⁽¹⁴⁾,11,15-hexaen-5-yl-but-3-enyl)-phenyl-amine 

Relevant articles and documents

Contractive Annulation: A Strategy for the Synthesis of Small, Strained Cyclophanes and Its Application in the Synthesis of [2](6,1)Naphthaleno[1]paracyclophane

A new synthetic strategy (contractive annulation) for the synthesis of highly strained cyclophanes has been conceived and its viability has been demonstrated through a nine-step synthesis of [2](6,1)naphthaleno[1]paracyclophane from [2.2]paracyclophane.

Synthesis of a [2.2]paracyclophane based planar chiral palladacycle by a highly selective kinetic resolution/C-H activation reaction

Kinetic resolution of racemic 4-N,N-dimethylaminomethyl[2.2]paracyclophane with 50% sodium tetrachloropalladate and (R)-N-acetylphenylalanine under basic conditions resulted in the formation of a (Sp)-planar chiral palladacycle (35%, >99% ee). Similarly use of 100 mol% sodium tetrachloropalladate resulted in higher levels of conversion and recovery of (Sp)-4-N,N-dimethylaminomethyl[2.2]paracyclophane (41%, >97% ee).

Photochromism of acetyl-cyclophanochromene: Intriguing stabilization of photogenerated colored o-quinonoid intermediates

The photochromism of a chromene annulated on [2.2]paracyclophane, Ac-CPC, was investigated. Whereas the parent chromene 2,2-diphenylbenzopyran shows photoinduced coloration only at very low temperatures, acetyl-cyclophanochromene Ac-CPC was found to exhib

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Multigram-Scale Kinetic Resolution of 4-Acetyl[2.2]Paracyclophane via Ru-Catalyzed Enantioselective Hydrogenation: Accessing [2.2]Paracyclophanes with Planar and Central Chirality

[2.2]Paracyclophane (PCP) derivatives have been promising platforms to study the element of planar chirality and through-space electronic communications in π-stacked molecular systems. To access enantiomerically pure derivatives thereof, a kinetic resolut