58010-00-7Relevant academic research and scientific papers
Gold(I)-catalyzed formation of 3-pyrazolines through cycloaddition of diaziridine to alkynes
Capretto, David A.,Brouwer, Chad,Poor, Catherine B.,He, Chuan
supporting information; scheme or table, p. 5842 - 5845 (2011/12/15)
This work reports the high-yield formation of pyrazoline derivatives mediated by gold(I) catalysts. The reaction utilizes a diaziridine, which has seen only limited usage in organic methodology. Mechanistic studies suggest a gold-mediated opening of the d
PREPARATIVE SEPARATIONS AND RACEMIZATIONS OF ENANTIOMERIC DIAZIRIDINES
Mintas, M.,Mannschrenk, A.,Klasinc, L.
, p. 867 - 871 (2007/10/02)
Preparative separations or enrichments of enantiomers of diaziridines 1, 2, and 5 were achieved by liquid chromatography on triacetylcellulose, (+)-1 and (+)-2 being isolated almost pure (Table 1).Enantiomeric purities were determined by 1H NMR in the pre
