58058-40-5

Basic information

• Product Name: Benzenecarboximidamide, N-(2-chlorophenyl)-
• CAS NO: 58058-40-5
• Molecular Formula: C13H11ClN2
• Molecular Weight: 230.697
• Mol File: 58058-40-5.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzenecarboximidamide, N-(2-chlorophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenecarboximidamide, N-(2-chlorophenyl)-(58058-40-5)
• EPA Substance Registry System: Benzenecarboximidamide, N-(2-chlorophenyl)-(58058-40-5)

Safety Data

• Hazardous Substances Data: 58058-40-5(Hazardous Substances Data)

Upstream product

• 100-47-0 benzonitrile 
• 95-51-2 o-chloroaniline 
• 3296-07-9 1-azido-2-chlorobenzene 

Downstream Products

• 85739-13-5 5-chloro-1-ethyl-3-phenyl-1λ⁴,2,4-benzothiadiazine 
• 58058-52-9 8-chloro-2-phenylquinazoline 
• 69709-68-8 5-chloro-1-(4-methylphenyl)-3-phenyl-1λ⁴,2,4-benzothiadiazine 
• 85616-09-7 5-chloro-1-morpholino-3-phenyl-1λ⁴,2,4-benzothiadiazine 
• 81568-76-5 1-(2-chlorophenyl)-2-phenyl-1H-benzo[d]imidazole 
• 1427216-62-3 C₇₃H₉ClN₂ 
• 97627-36-6 [2-(2-Chloro-phenyl)-3-phenyl-2H-[1,2,4]thiadiazol-(5E)-ylidene]-phenyl-amine 
• 82636-03-1 1-(2-Chloro-phenyl)-6-oxo-2-phenyl-1,6-dihydro-pyrimidine-5-carboxylic acid ethyl ester 

Relevant articles and documents

Transition-Metal-Free Synthesis of 1,2-diphenyl-1H-benzo[d] Imidazole Derivatives from N-phenylbenzimidamides and Cyclohexanones

A transition-metal-free strategy for the formation of 1,2-diphenyl-1H-benzo[d] imidazoles from N-phenylbenzimidamides and cyclohexanones is introduced. This is the first report on the direct synthesis of 1,2-diphenyl-1H-benzo[d] imidazoles from cyclohexanones and N-phenylbenzimidamides via iodine- promoted oxidative cyclization. Non-aromatic cyclohexanones were smoothly dehydrogenated, and acted as an aryl source using oxygen as a green oxidant. The catalytic use of iodine makes this method quite simple, more economical and convenient. Under optimized conditions, various substituted 1,2-diphenyl-1H-benzo[d] imidazoles were smoothly reacted, and the desired substituted imidazoles were generated with moderate to excellent yields. (Figure presented.).

Synthesis and structure of aroylamidines and N-arylbenzamidines hydrochlorides

Aroylamidines can be obtained as salts in a reaction of the corresponding arylcarbonitriles with anhydrous ethanol in the presence of dry HCl followed by treating intermediate imidoesters with alcoholic solution of ammonia. N-Arylbenzamidines are obtained by reacting benzonitrile with arylamines in the presence of AlCl3. The structure of arylamines and the reaction conditions signifi cantly affect the yield of the target product, and sometimes the very possibility of its preparation. Pleiades Publishing, Ltd., 2012.

Samarium diiodide induced reductive coupling of nitriles with azides

A series of amidine derivatives were synthesized via the intermolecular reductive coupling of nitriles with azides induced by samarium diiodide in good yields under mild and neutral conditions.