5807-64-7

Usage

Synthesis Reference(s)

Tetrahedron Letters, 20, p. 1063, 1979 DOI: 10.1016/S0040-4039(01)87192-6

Upstream product

• 186581-53-3 diazomethane 
• 15435-71-9 sodium acetoacetonate 
• 121619-96-3 copper(I) 2-bromobenzoate 
• 75732-01-3 mesitylcopper(I) 
• 16231-67-7 methyl 2'-formyl-[1,1'-biphenyl]-2-carboxylate 
• 610-97-9 o-iodo-methyl-benzoic acid 
• 67-56-1 methanol 
• 6623-54-7 5,8-Dimethoxy-5,8-dihydro-dibenzo[d,f][1,2]dioxocin 
• 201230-82-2 carbon monoxide 
• 104-83-6 1-Chloro-4-(chloromethyl)benzene 
• 93-58-3 benzoic acid methyl ester 
• 609-73-4 o-nitroiodobenzene 
• 342-54-1 2-(methoxycarbonyl)benzenediazonium tetrafluoroborate 
• 610-94-6 2-bromobenzoic acid methyl ester 

Downstream Products

• 4269-19-6 9-oxo-fluorene-4-carboxylic acid methyl ester 
• 6223-83-2 9-oxo-9H-fluorene-4-carboxylic acid 
• 18076-62-5 2,2'-bis(hydroxyldiphenylmethyl)biphenyl 
• 86-73-7 9H-fluorene 
• 486-25-9 9-fluorenone 
• 1689-64-1 9-Fluorenol 
• 84-11-7 9,10-phenanthrenequinone 
• 194494-02-5 2,2'-bis[bis(p-methoxyphenyl)hydroxymethyl]biphenyl 
• 14665-22-6 2-hydroxymethyl-2'-formylbiphenyl 
• 7111-68-4 2'-methylbiphenyl-2-carboxaldehyde 
• 1210-05-5 Biphenyl-2,2'-dicarbaldehyde 
• 107011-08-5 bis{2,2'-bis(2-imidazolyl)biphenyl} 
• 126664-76-4 2,2'-bis(2-imidazolinyl)biphenyl 
• 776-35-2 9,10-dihydrophenanthrene 

Relevant academic research and scientific papers

Structural elucidation of thermolysis products of methyl N-methyl-N-nitrosoanthranilate

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A highly selective palladium bis(acetoacetonate)/copper(I) chloride [Pd(acac)2/CuCl] catalytic system for the preparation of dibenzopyranones has been developed. Tandem decarboxylative coupling and lactonization can be realized in one pot using commercially available starting materials. The reaction proceeded well for a range of different substrates. Copyright

Neopentylglycolborylation of ortho -substituted aryl halides catalyzed by NiCl2-Based mixed-ligand systems

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Phosphinates as new electrophilic partners for cross-coupling reactions

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We found a brand-new method for the generation of aryne from methyl 2-bromobenzoates via the Pd-mediated concomitant δ-carbon elimination and decarboxylation. The generated arynes underwent Pd-mediated [2+2+2] cycloaddition to give triphenylenes.

Copper(I)-catalysed homo-coupling of aryldiazonium salts: synthesis of symmetrical biaryls

Copper(I) triflate acts as an efficient stoichiometric reagent for the homo-coupling of aryldiazonium salts bearing electron-withdrawing group(s), to yield symmetrical biaryls in acetonitrile under mild reaction conditions. Aryldiazonium salts bearing electron-donating groups undergo the reaction by using catalytic amounts of a copper complex prepared in situ from copper(II) triflate and 2,2′-bipyridine with metallic copper as an ultimate reductant.

Synthesis of quinolines, 2-quinolones, phenanthridines, and 6(5H)-phenanthridinones via palladium[0]-mediated Ullmann cross-coupling of 1-bromo-2-nitroarenes with β-halo-enals, -enones, or -esters

Palladium[0]-mediated Ullmann cross-coupling of 1-bromo-2-nitrobenzene (1 R = H) and its derivatives with a range of β-halo-enals, -enones, or -esters readily affords the corresponding β-aryl derivatives, which are converted into the corresponding quinolines, 2-quinolones, phenanthridines, or 6(5H)-phenanthridinones on reaction with dihydrogen in the presence of Pd on C or with TiCl3 in aqueous acetone.

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The Hurtley reaction III. A reactivity study of copper(I) 2-halobenzoates either as pure reagents, or under Hurtley reaction conditions, and as a part of mixed (benzoato)(mesityl)copper(I) clusters

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