58081-06-4

Basic information

• Product Name: Silane, bicyclo[4.4.1]undeca-1,3,5,7,9-pentaen-2-yltrimethyl-
• CAS NO: 58081-06-4
• Molecular Formula: C14H18Si
• Mol File: 58081-06-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silane, bicyclo[4.4.1]undeca-1,3,5,7,9-pentaen-2-yltrimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, bicyclo[4.4.1]undeca-1,3,5,7,9-pentaen-2-yltrimethyl-(58081-06-4)
• EPA Substance Registry System: Silane, bicyclo[4.4.1]undeca-1,3,5,7,9-pentaen-2-yltrimethyl-(58081-06-4)

Safety Data

• Hazardous Substances Data: 58081-06-4(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 15825-92-0 2-bromo-1,6-methano[10]annulene 

Downstream Products

• 2443-46-1 1,6-methano[10]annulene 

Relevant articles and documents

SOME GROUP IVB DERIVATIVES OF 1,6-METHANOANNULENE. SYNTHESIS, SUBSTITUENT EFFECTS AND REACTIVITY

Certain Group IVB derivatives of 1,6-methanoannulene have been synthesised, and their 13C nuclear magnetic resonance spectra recorded and assigned, to provide a measure of the substituent effects exerted by metalloid-containing groups in this non-benzenoid aromatic system.Comparisons are made with the corresponding naphthalene and some anthracene derivatives.Protiodemetallations of a number of arylsilanes and -stannanes have been examined, and in protiodestannyletion by CH3CO2H/dioxane at 27 deg C (an electrophilic aromatic substitution) the α- (or 2-) posititon of 1,6-methanoannulene is ca. 35 times as reactive as the α (or 1-) position of naphthalene, whereas in protiodesilylation by CF3CO2H/CH3CO2H at 27 deg C it is ca. 700 times the more reactive.