58119-99-6Relevant academic research and scientific papers
Bis-sulfamyl imines: Potent substrates for asymmetric additions of arylboroxines under rhodium catalysis
Crampton, Rosemary,Woodward, Simon,Fox, Martin
supporting information; experimental part, p. 903 - 906 (2011/06/19)
Bis-sulfamyl imines are shown to be potentially ideal substrates for rhodium-catalysed asymmetric additions of arylboron nucleophiles as they show: (i) near perfect enantioselectivities (11 examples, 98-99+% ee), (ii) good to excellent diastereoselectivities (10-32:1 rac:meso), and (iii) high functional group tolerance in removal of the low molecular weight protecting group via mild heating in aqueous pyridine.
Intramolecular imine cross-coupling in dibenzylidine sulfamides: Synthesis of unsymmetrical 1,2-diaryl ethanediamines
Pansare, Sunil V.,Malusare, Mahesh G.
, p. 2859 - 2862 (2007/10/03)
Intramolecular reductive cross-coupling of unsymmetrical dibenzylidene sulfamides generates the corresponding cyclic sulfamides in good yield. These intermediates are readily converted to the free, unsymmetrical 1,2-diaryl ethanediamines.
A NEW SYNTHESIS OF PRIMARY AMINES FROM DIARYLIDENESULFAMIDES
Davis, Franklin A.,Giangiordano, Mark A.,Starner, William E.
, p. 3957 - 3960 (2007/10/02)
Addition of organometallic reagents to diarylidenesulfamides affords, after hydroylsis, primary amines illustrating the application of sulfamides as amino protecting groups.
