58131-63-8

Upstream product

• 113204-09-4 [(dimethylcarbamoyl)methyl]triphenylphosphonium chloride 
• 603-35-0 triphenylphosphine 
• 2675-89-0 2-chloro-N,N-dimethylacetamide 

Downstream Products

• 603-35-0 triphenylphosphine 
• 5830-31-9 N,N-dimethyl-3-phenylpropanamide 
• 17431-39-9 (E)-N,N-dimethylcinnamamide 
• 103-41-3 (E)-cinnamic acid benzyl ester 
• 22767-96-0 Benzyl 3-phenylpropionate 
• 138176-25-7 AuCl(CH(P(C₆H₅)3)C(O)N(CH₃)2) 
• 207859-11-8 [PdCl(C₂₁H₂₀P)(CH(CON(CH₃)2)P(C₆H₅)3)] 
• 207859-09-4 [PdBr(C₃H₅)(CH(CON(CH₃)2)P(C₆H₅)3)] 
• 207859-12-9 [PdCl(C₆F₅)(SC₄H₈)(CH(CON(CH₃)2)P(C₆H₅)3)] 
• 207927-37-5 [PdCl₂(P(C₆H₅)3)(CH(CON(CH₃)2)P(C₆H₅)3)] 
• 207859-13-0 [PdCl(C₉H₁₂N)(CHCON(CH₃)2)P(C₆H₅)3] 
• 207859-08-3 Pd(C₉H₁₂N)(NC₅H₅)(CHCON(CH₃)2)P(C₆H₅)3⁽¹⁺⁾*ClO₄^(1-) = [Pd(C₉H₁₂N)(NC₅H₅)(CHCON(CH₃)2)P(C₆H₅)3]ClO₄ 
• 207859-04-9 Pd(C₉H₁₂N)(H₂O)(CHCON(CH₃)2)P(C₆H₅)3⁽¹⁺⁾*ClO₄^(1-) = [Pd(C₉H₁₂N)(H₂O)(CHCON(CH₃)2)P(C₆H₅)3]ClO₄ 

Relevant academic research and scientific papers

Quaternary Charge-Transfer Complex Enables Photoenzymatic Intermolecular Hydroalkylation of Olefins

Intermolecular C-C bond-forming reactions are underdeveloped transformations in the field of biocatalysis. Here we report a photoenzymatic intermolecular hydroalkylation of olefins catalyzed by flavin-dependent 'ene'-reductases. Radical initiation occurs via photoexcitation of a rare high-order enzyme-templated charge-transfer complex that forms between an alkene, α-chloroamide, and flavin hydroquinone. This unique mechanism ensures that radical formation only occurs when both substrates are present within the protein active site. This active site can control the radical terminating hydrogen atom transfer, enabling the synthesis of enantioenriched γ-stereogenic amides. This work highlights the potential for photoenzymatic catalysis to enable new biocatalytic transformations via previously unknown electron transfer mechanisms.

SYNTHESIS OF SELENOPSILOCINE (3-DIMETHYLAMINOETHYL-4-HYDROXYBENZOSELENOPHENE)

Starting from the known 6-methoxyanthranilic acid (5), we have synthesized in six steps the selenium analogue of psilocine (1c).The key intermediate is the 4-methoxyselenoindoxyl (8), which is condensed with the dimethylaminocarbamoylmethylenetriphenylpho

Synthesis and Structural Characterization of Gold-(I), -(III) and Silver(I) Complexes of the Ylide Ligand Ph3P=CHC(O)NMe2. Crystal Structure of >ClO4

The reaction between (tht = tetrahydrothiophene) and the ylide Ph3P=CHC(O)NMe2 gives > 1, which reacts with chlorine to give > 2 and with the same ylide and NaClO4 to form 2>ClO4 3.The analogous silver complex 2>ClO4 4 is obtained by the reaction of AgClO4 with the ylide in molar ratio 1: 2.The phosphonium salt ClO4 reacts with (acac = acetylacetonate) to give (PPh3)>ClO4 5 or >ClO4 6 depending on the reaction conditions.The structure of 6 was confirmed by an X-ray diffraction study at -95 deg C , a = 11.572(3), b = 11.836(3), c = 21.627(7) Angstroem, α = 78.29(2), β = 87.19(2), γ = 75.65(2) deg, R = 0.076>; the Au...Au bond length is 2.938(1) Angstroem.