58245-77-5Relevant academic research and scientific papers
1,3-Methoxy rearrangement of masked o-benzoquinones: A novel synthesis of p-quinol ethers
Yang, Ching-Shun,Liao, Chun-Chen
, p. 4809 - 4812 (2008/03/15)
(Chemical Equation Presented) p-Quinol ethers are valuable synthons in synthetic organic chemistry. MOBs 1a-1l can be converted to p-quinol ethers 2a-2i in a highly efficient manner via 1,3-methoxy migration catalyzed by Lewis acids. The migration was fou
Bromide-assisted oxidation of substituted phenols with hydrogen peroxide to the corresponding p-quinol and p-quinol ethers over WO4 2--exchanged layered double hydroxides
Sels,De Vos,Jacobs
, p. 310 - 313 (2007/10/03)
A simple and efficient one-pot synthesis of p-quinols and their ethers occurs over tungstate-exchanged layered double hydroxides (WO4 2--LDHs), which catalyze the bromide-assisted oxidation of substituted phenols to the corresponding 4-alkoxy- and 4-hydroxycyclohexa-2,5- dienones in high yields (see scheme).
