58258-94-9

Upstream product

• 623-27-8 terephthalaldehyde, 
• 98-86-2 acetophenone 
• 626-19-7 Isophthalaldehyde 
• 20913-05-7 (Benzoylmethylene)triphenylphosphorane 
• 108-36-1 1,3-dibromobenzene 

Downstream Products

• 97923-51-8 1,3-Bis-<3-oxo-5-phenyl-cyclohex-4-enyl>-benzol 
• 850408-41-2 (E)-3-[3-(4-Benzoyl-3-phenyl-4,5-dihydro-isoxazol-5-yl)-phenyl]-1-phenyl-propenone 
• 850408-44-5 {5-[3-(4-benzoyl-3-phenyl-4,5-dihydro-isoxazol-5-yl)-phenyl]-3-phenyl-4,5-dihydro-isoxazol-4-yl}-phenyl-methanone 
• 850408-42-3 (E)-3-{3-[4-Benzoyl-3-(4-chloro-phenyl)-4,5-dihydro-isoxazol-5-yl]-phenyl}-1-phenyl-propenone 
• 850408-45-6 [5-{3-[4-benzoyl-3-(4-chloro-phenyl)-4,5-dihydro-isoxazol-5-yl]-phenyl}-3-(4-chloro-phenyl)-4,5-dihydro-isoxazol-4-yl]-phenyl-methanone 
• 1335292-76-6 C₄₈H₄₀O₂P₂ 
• 1355537-23-3 C₄₈H₄₀O₂P₂ 
• 16716-13-5 m-quinquephenyl 
• 850408-39-8 [5-{3-[4-benzoyl-5-(4-chloro-phenyl)-2-phenyl-3,4-dihydro-2H-pyrazol-3-yl]-phenyl}-3-(4-chloro-phenyl)-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl]-phenyl-methanone 
• 850408-38-7 {5-[3-(4-benzoyl-2,5-diphenyl-3,4-dihydro-2H-pyrazol-3-yl)-phenyl]-1,3-diphenyl-4,5-dihydro-1H-pyrazol-4-yl}-phenyl-methanone 
• 850408-35-4 3-[3-(4-benzoyl-2,5-diphenyl-3,4-dihydro-2H-pyrazol-3-yl)-phenyl]-1-phenyl-propenone 
• 850408-36-5 3-{3-[4-benzoyl-5-(4-chloro-phenyl)-2-phenyl-3,4-dihydro-2H-pyrazol-3-yl]-phenyl}-1-phenyl-propenone 

Relevant academic research and scientific papers

Catalytic Synthesis of Chalcones and Pyrazolines Using Nanorod Vanadatesulfuric Acid: An Efficient and Reusable Catalyst

Nanorod vanadatesulfuric acid (VSA NRs), as a recyclable and ecologically benign catalyst, was used for the one-pot synthesis of chalcones and 1,3,5-triaryl-2-pyrazolines (TAPs). Chalcones were prepared via the condensation of substituted acetophenones with aryl-aldehydes under solvent-free conditions. Subsequently, the synthesized chalcones were used for the catalytic synthesis of TAPs via two-component condensation with phenyl hydrazine in refluxing ethanol. VSA is easily prepared by a simple reaction of chlorosulfonic acid and sodium metavanadate of high purity. Compared to conventional procedures, the present protocol offers several advantages such as simplicity of the procedure, appropriate reaction times, high to excellent yields, easily work-up, recoverability, and reusability of the catalyst, and simple purification of the products.

Versatile syntheses of optically pure pce pincer ligands: Facile modifications of the pendant arms and ligand backbones

A series of chiral C-stereogenic PCP and PCN ligand precursors were prepared in situ from inexpensive achiral starting materials via a simple catalytic asymmetric P-H addition reaction in good overall yields. This facile catalytic method of preparing the ligand backbones renders easy and economical modifications of the electronically crucial para-substituent, chiral functionalities, and donor atoms for different transition metal ions. A one-pot synthetic procedure was used efficiently to prepare the corresponding optically pure pincer complexes. All the new complexes were characterized by NMR and mass spectroscopy. The molecular structures of several selected complexes have also been elucidated by X-ray crystallography. Preliminary studies indicated that minor structural changes on these novel pincer complexes affect their chemical properties significantly when they were applied as catalysts for the reaction between diphenylphosphine and chalcone.

Preparations and spin-spin interactions of 4,4′-(m-Phenylene)bis(1-methyl-2,6-diphenylpyridinyl) and its analogue

4,4′-(1-Phenylene)bis(1-methyl-2,4,6-triphenylpyridinium) (12+) and 4,4′,4″-(benzene-1,3,5-triyl)tris(1-methyl-2,4,6- triphenylpyridinium) (23+) were synthesized and their metal reductions were studied; 12+ gave the triplet diradical (1) in the ground state, and 23+ produced also a triplet diradical and the expected quartet species was not observed.