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5827-73-6

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5827-73-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 5827-73-6 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 5,8,2 and 7 respectively; the second part has 2 digits, 7 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 5827-73:
(6*5)+(5*8)+(4*2)+(3*7)+(2*7)+(1*3)=116
116 % 10 = 6
So 5827-73-6 is a valid CAS Registry Number.

5827-73-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name N-butan-2-ylpropanamide

1.2 Other means of identification

Product number -
Other names Propionsaeure-N-sek.-butylamid

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:5827-73-6 SDS

5827-73-6Downstream Products

5827-73-6Relevant articles and documents

Synthesis and FTIR spectroscopic study of some N-monosubstituted propanamides

Antonovi?,Stojanovi?,Bo?i?,Nikoli?,Petrovi?

, p. 421 - 423 (2007/10/03)

In the present work we investigated the conformations of some N-mono-substituted propanamides of general formula CH3CH2CONHR, wherein R is chosen from n-(C1-C9)alkyl, cyclo(C3-C6)alkyl, some branched (C3-C6)alkyl or phenyl. The amides were synthesised by the well known Schotten-Baumann reaction-acylation of the corresponding amines with propionyl chloride. On the basis of FTIR data for diluted solutions (concentrations below 10-3 mol dm-3) of N-mono-substituted propanamides in carbon tetrachloride, chloroform, dichloromethane, or a 1:1.5 mixture of benzene and carbon tetrachloride the exact position of the N-H stretching band was established. For spectroscopic data the different conformational isomers were assigned and its structures unequivocally proven. These results are in good accordance with 1H NMR and MS data.

Ester Aminolysis: New Reaction Series for the Quantitative Measurement of Steric Effects

DeTar, DeLos F.,Delahunty, Claire

, p. 2734 - 2739 (2007/10/02)

Further development of theoretical methods for computing steric effects on chemical reactivity requires a large body of new reliable quantitative data for calibration and for testing.We report here on design criteria for reaction series suitable for obtaining these data and on a successful implementation that shows promise of providing access to a particularly broad range of steric hindrance and which additionally has shown a new form of steric hindrance.The series examined in the present study is ester aminolysis in the form RCOOC6H4NO2-p + R'NH2 in acetonitrile solution.A primary purpose of the examination has been to ascertain whether aminolysis may be a useful general series or whether known or unexpected complications might render it unsuitable.We have measured rate constants for a matrix of reactions using five different R groups and four different R' groups, each reaction at a series of concentrations of amine.This is the first systematic study of the sumultaneous action of steric hindrance effects in both the acylating agent and the entering nucleophile.The reactions showed both a second-order term k2 and a relatively less important third-order term k32.The Taft equation was applied to subsets of the rate constants.For each amine there were data for a set of esters for which the R group was the variable.The slopes ρs for these sets were nearly unity.For each ester there were corresponding data for a series of amine reactions in which R' was the variable.These sets also gave good correlations, but the slopes ρs' were considerably larger, about 2.3.This unusually large difference in response to structural effects in the acylating agent and in the nucleophile is unexpected and appears to arise from a new type of steric hindrance.An obvious explanation based on bond lengths proves to be quantitatively insufficient; that explanation postulates that there is greater hindrance for the amine because the C-N bond is short in comparison with the C-C bond.The difference may be due instead to a requirement for special orientation within the transition state, a matter currently under theoretical investigation.The k2 and the k3 sets gave similar correlations, an important finding in at least two respects.It means that steric effects are well-defined in this example of ester aminolysis, and it means also that the extra molecule of amine is far enough from the reaction center so that no additional steric hindrance results.The reactions observed in the present study cover a range of 5 powers of 10 in relative rate constants.Preliminary studies with other examples of aminolysis suggest that a range of relative rate constants covering well in excess of 12 powers of 10 should be observable.

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