58277-26-2

Basic information

• Product Name: Ethanone, 1-(1,3-dithian-2-yl)- (9CI)
• Synonyms: Ethanone, 1-(1,3-dithian-2-yl)- (9CI)
• CAS NO: 58277-26-2
• Molecular Formula: C₆H₁₀OS₂
• Molecular Weight: 162.273
• Product Categories: ACETYLGROUP
• Mol File: 58277-26-2.mol
• Article Data: 9

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Ethanone, 1-(1,3-dithian-2-yl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(1,3-dithian-2-yl)- (9CI)(58277-26-2)
• EPA Substance Registry System: Ethanone, 1-(1,3-dithian-2-yl)- (9CI)(58277-26-2)

Safety Data

• Hazardous Substances Data: 58277-26-2(Hazardous Substances Data)

Upstream product

• 65644-59-9 1,3-dithianyl carbanion 
• 141-78-6 ethyl acetate 
• 36049-90-8 2-lithio-1,3-dithiane 
• 505-23-7 1,3 dithiane 
• 78191-00-1 N-Methoxy-N-methylacetamide 
• 109-80-8 1.3-propanedithiol 
• 513-88-2 1,1-Dichloroacetone 

Downstream Products

• 137871-74-0 2-((E)-5-(phenylsulfonyl)-4-pentenyl)-2-(2-((methoxycarbonyl)oxy)-3-((trimethylsilyl)methyl)-3-buten-2-yl)-1,3-dithiane 

Relevant articles and documents

Studies towards the total synthesis of batzelladine A

Application of a diastereoselective three-component coupling to the bicyclic core of the batzelladine alkaloids is described. The synthesis features the elaboration of glutamic acid by use of Eschenmoser sulfide contraction. An earlier approach is also included, which shows some limitations of dithiane chemistry when applied to the particular compounds required for this target.

A Chemoenzymatic Synthesis of (R)-2-(1-Hydroxyethyl)-2,3-dithiane

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Lewis acid mediated addition of 2-acyl-1,3-dithianes to α,β-unsaturated ketones: Synthesis of cyclohexenedione mono-dithioacetals

2-Acyl-1,3-dithianes undergo Lewis acid-mediated conjugate addition to α,β-unsaturated ketones to provide 1,5-diketones which suffer base-catalyzed intramolecular aldol reaction to produce monodithioacetals of cyclohex-2-en-1,4-diones and cyclohex-3-en-1,