58316-39-5

Basic information

• Product Name: 2-Butenoic acid, 3-(benzoyloxy)-, ethyl ester, (E)-
• CAS NO: 58316-39-5
• Molecular Formula: C13H14O4
• Molecular Weight: 234.252
• Mol File: 58316-39-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Butenoic acid, 3-(benzoyloxy)-, ethyl ester, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butenoic acid, 3-(benzoyloxy)-, ethyl ester, (E)-(58316-39-5)
• EPA Substance Registry System: 2-Butenoic acid, 3-(benzoyloxy)-, ethyl ester, (E)-(58316-39-5)

Safety Data

• Hazardous Substances Data: 58316-39-5(Hazardous Substances Data)

Upstream product

• 98-88-4 benzoyl chloride 
• 123-54-6 acetylacetone 
• 141-97-9 ethyl acetoacetate 

Downstream Products

• 30801-96-8 (E)-3-methylhex-2-en-1-ol 
• 51751-37-2 2-Methyl-4-oxo-4H-<1>benzopyran-3-carboxylic acid 

Relevant articles and documents

Synthesis of isocoumarins via silver(I)-mediated annulation of enol esters

Silver-mediated annulation of 2-iodo enol esters leading to 4- and 3,4-substituted isocoumarins was accomplished selectively at room temperature. Coupling of 2-iodo benzoic acids with enolates that were produced in situ from the simple esters was also performed to produce isocoumarins under analogous reaction conditions. Owing to the mildness of the current protocol, 4-acyl 3-substituted isocoumarins were efficiently produced without any deacylation.