58321-86-1Relevant academic research and scientific papers
Enantioselective addition of thioacetic acid to nitroalkenes via N-sulfinyl urea organocatalysis
Kimmel, Kyle L.,Robak, MaryAnn T.,Ellman, Jonathan A.
scheme or table, p. 8754 - 8755 (2009/12/04)
(Chemical Equation Presented) The highly enantioselective addition of thioacetic acid to nitroalkenes using a new sulfinyl urea organocatalyst is described. The addition of thioacetic acid proceeds in high yields and enantioselectivities for a variety of
Highly stereoselective nitration of chalcone derivatives with nitric oxide
Li, Rui,Liu, Zhongquan,Zhou, Yulu,Wu, Longmin
, p. 1367 - 1368 (2007/10/03)
A novel nitration of chalcone derivatives with nitric oxide affords E-α-nitropropenones exclusively in good yield. The reaction is most likely initiated by electrophilic addition of nitric dioxide to the C=C double bond at the α-position. Georg Thieme Ver
REACTIONS DES METHYLAZIDE ET PHENYLAZIDE AVEC QUELQUES ALCYNES ET OLEFINES α-NITREES. SYNTHESE REGIOSPECIFIQUE DES 1,2,3 TRIAZOLES
Piet, J. C.,Hetet, G. Le,Cailleux, P.,Benhaoua, H.,Carrie, R.
, p. 33 - 44 (2007/10/03)
The reactions of alkynes and α-nitro-olefines with methylazide and phenylazide was studied.In contrast to known reactions with alkynes which are non-regioselective, methylazide and phenylazide react regiospecifically with α-nitro-olefines and give only one type of triazole after elimination of HNO2.These reactions are very useful synthetic approaches to 1,2,3 triazoles.
