78787-97-0Relevant articles and documents
Multielectron oxidation of anthracenes with one-electron oxidant via water-accelerated electron-transfer disproportionation of the radical cations as the rate-determining step
Fukuzumi,Nakanishi,Tanaka
, p. 11212 - 11220 (1999)
The six-electron oxidation of anthracene and the four-electron oxidation of 9-alkylanthracene occurred with [Ru(bpy)3]3+ (bpy = 2,2-bipyridine) in acetonitrile (MeCN) containing H2O to yield anthraquinone and 10-alkyl-10-h
PHOTOCHEMICAL REACTION OF 9,10-ANTRAQUINONE WITH CHLOROFORM AND TOLUENE
Loskutov, V. A.,Konstantinova, A. V.,Fokin, E. P.
, p. 902 - 903 (1981)
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Regioselective Alkylation of Anthrahydroquinone and Anthrone in Water with Quinonemethides and Other Alkylating Agents
Dimmel, Donald R.,Shepard, Donaline
, p. 22 - 29 (2007/10/02)
Antrahydroquinone (AHQ) and anthrone are alkylated in the C10 position by quinonemethides, generated in situ from p-acetoxybenzyl chlorides, to give adducts 13-15, 24, 25, 28, 29, and 32.Aqueous alkylations of AHQ with methyl vinyl ketone, cinnamaldehyde, and benzyl chloride also produces C10-substituted 10-hydroxyanthrones.Simple ketones and aldehydes do not, however, alkylate AHQ in aqueous alkali.