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Usage

Uses

Used in Chemical Synthesis:
(E)-1,4-BIS(-4-BROMOSTYRYL)BENZENE is used as a chemical intermediate for the synthesis of various compounds. Its unique structure, which includes bromine atoms and benzene rings, makes it a valuable building block in the production of dyes, optical brighteners, and other specialty chemicals.
Used in Research Applications:
In the scientific community, (E)-1,4-BIS(-4-BROMOSTYRYL)BENZENE is employed as a research compound to study its properties and potential applications. Its reactivity and interaction with other chemicals can provide insights into the development of new materials and processes.
Used in Pharmaceutical Industry:
(E)-1,4-BIS(-4-BROMOSTYRYL)BENZENE is used as a starting material in the synthesis of pharmaceutical compounds. Its structural features may contribute to the development of new drugs with potential therapeutic applications.
Used in Material Science:
In the field of material science, (E)-1,4-BIS(-4-BROMOSTYRYL)BENZENE is used as a component in the development of advanced materials with specific properties, such as improved conductivity or enhanced stability. Its incorporation into these materials can lead to innovative applications in various industries.
Used in Dye and Pigment Production:
(E)-1,4-BIS(-4-BROMOSTYRYL)BENZENE is used as a key ingredient in the production of dyes and pigments. Its chemical structure allows for the creation of vibrant colors and hues, making it an essential component in the formulation of various colorants used in industries such as textiles, plastics, and printing.

Upstream product

• 1519-47-7 [p-phenylenebis(methylene)]bis[triphenylphosphonium] dichloride 
• 1122-91-4 4-bromo-benzaldehyde 
• 38186-51-5 diethyl (4-bromobenzyl)phosphonate 
• 623-27-8 terephthalaldehyde, 
• 40817-03-6 p-xylenebis(triphenylphosphonium) dibromide 
• 115055-85-1 bromo-[(4-bromophenyl)methyl]zinc 
• 4546-04-7 tetraethyl 1,4-xylylenediphosphonate 
• 106-42-3 para-xylene 
• 589-15-1 1-bromomethyl-4-bromobenzene 
• 1123168-00-2 1,3-bis[(E)-4-bromostyryl]tetramethyldisiloxane 
• 624-38-4 para-diiodobenzene 
• 35335-16-1 1,4-bis(bromomethyl)-2,5-dibromobenzene 
• 1074-24-4 2,5-dibromo-p-xylene 
• 35335-17-2 [2,5-dibromo-4-(diethoxyphosphorylmethyl)-benzyl]phosphonic acid diethyl ester 

Downstream Products

• 131941-39-4 1,4-bis[2-(4-bromophenyl)ethynyl]benzene 
• 155600-95-6 4-((E)-2-(4-[(E)-2-(4-formylphenyl)ethenyl]phenyl)ethenyl)benzaldehyde 
• 156816-40-9 (E,E,E,E)-tetraethyl 1,4-phenylenebis(1,2-ethenyl-4-phenyl-1,2-ethenyl-4-phenylphosphonate) 
• 1388147-82-7 1,4-bis[(E)-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)styryl]benzene 
• 16726-75-3 1,4-bis((E)-2-([1,1′-biphenyl]-4-yl)vinyl)benzene 

Relevant academic research and scientific papers

Polyaniline-anchored palladium catalyst-mediated Mizoroki-Heck and Suzuki-Miyauraa reactions and one-pot Wittig-Heck and Wittig-Suzuki reactions

A polyaniline-anchored palladium catalyst was prepared and screened for coupling reactions of aryl halides. The robust and recyclable catalyst was effective in Mizoroki-Heck and Suzuki-Miyaura reactions of aryl bromides and aryl iodides. The catalyst system was further employed for one-pot Wittig-Heck and Wittig-Suzuki combinations to build conjugated compounds in good conversions.

Gold(I) styrylbenzene, distyrylbenzene, and distyrylnaphthalene complexes: High emission quantum yields at room temperature

One gold(I)-substituted styrylbenzene, six digold(I) distyrylbenzenes, one tetragold distyrylbenzene, and four digold distyrylnaphthalene complexes were synthesized using base-promoted auration, alkynylation, triazolate formation, and Horner-Wadsworth-Emmons reactions. The gold(I) fragments are either σ-bonded to the aromatic system, or they are attached through an alkynyl or triazolate spacer. Product formation was monitored using 31P{ 1H} NMR spectroscopy. Systems in which gold(I) binds to the central benzene ring or the terminal phenyl rings were designed. All of these complexes have strong ultraviolet absorptions and emit blue light. The position of the gold(I) attachment influences the luminescence efficiency. Complexes with two gold(I) fragments attached to the ends of the conjugated system have fluorescence quantum yields up to 0.94, when using 7-diethylamino-4- methylcoumarin as the emission standard. Density-functional theory calculations on three high-yielding emitters suggest that luminescence originates from the distyrylbenzene or -naphthalene bridge. Copyright

A convenient one-pot synthesis of bis[(E)-4-halostyryl]arene derivatives

A new convenient synthetic protocol for the one-pot stereoselective synthesis of bis[(E)-4-bromo(or chloro)styryl]arene derivatives via the sequential reaction of silylative-coupling of 4-halostyrenes with vinylsilanes followed by palladium-catalyzed cross-coupling 4-halostyrylsilanes with diiodoarenes, is described. The reaction leads to symmetrical bis[(E)-4-halostyryl]arene derivatives obtained in a stereocontrolled manner with high efficiency. Georg Thieme Verlag Stuttgart.

Palladium-catalyzed stereoselective synthesis of (E)-stilbenes via organozinc reagents and carbonyl compounds

In the presence of a catalytic amount of PdCl2(PPh 3)2 and a silylating agent, organozinc halides reacted with carbonyl compounds to give the corresponding (E)-stilbenes in good to excellent yields under mild conditions. The reaction mechanism is briefly discussed.

Intervalence transitions in the mixed-valence monocations of bis(triarylamines) linked with vinylene and phenylene-vinylene bridges

(E)-4,4′-Bis{bis(4-methoxyphenyl)amino}stilbene, 1, (E,E)-1,4-bis[4-{bis(4-methoxyphenyl)-amino}styryl]benzene, 2, and two longer homologues, (E,E,E)-4,4′-bis[4-{bis(4-methoxyphenyl)amino}-styryl] stilbene, 3, and (E,E,E,E)-1,4-bis(4-[4-{bis(4-methoxyphen

Design of ??-conjugated organic materials for one-dimensional energy transport in nanochannels

Various end-substituted distyrylbenzenes have been synthesized to serve as guest molecules in inclusion compounds to promote efficient energy transport along one-dimensional channels. Their optical and photophysical properties have been characterized at b

Triaryl boron-based A-π-A vs triaryl nitrogen-based D-π-D quadrupolar compounds for single- and two-photon excited fluorescence

(Equation Presented) Three new A-π-A-type compounds with trivalent boron, protected by two mesityl groups, as electron acceptor have been synthesized and investigated together with their two diphenylamino-ended D-π-D analogues. These boranes exhibit large two-photon absorption cross sections and high fluorescence quantum yields.

Synthesis, layer assembly, and fluorescence dynamics of poly(phenylenevinylene) oligomer phosphonates

We report the synthesis and spectroscopic study of a new molecularly engineered multilayer structure. The chromophore, which is an oligomer of poly(p-phenylenevinylene), is analogous to polymeric PPV which has been used in the fabrication of LEDs. This st

Synthesis and Absorption/Emission Spectral Properties of Styrylstilbene and Distyrylanthracene Derivatives

A series of para-substituted styrylstilbenes I and 9,10-distyrylanthracenes II was synthesized by Wittig or Arbusov-Horner reaction as a key step.Subsequently, systematic investigations were carried out on their absorption and fluorescence spectra, and th