584-94-1Relevant academic research and scientific papers
Silica-immobilized ionic liquid Br?nsted acids as highly effective heterogeneous catalysts for the isomerization of: N -heptane and n -octane
Al-Fatesh, Ahmed S.,Dhar, Abhishek,Fakeeha, Anis H.,Ibrahim, Ahmed A.,Khimani, Mehul,Patel, Hiren,Siva Kumar, Nadavala,Vekariya, Rohit L.
, p. 15282 - 15292 (2020/05/05)
Metal-free imidazolium-based ionic liquid (IL) Br?nsted acids 1-methyl imidazolium hydrogen sulphate [HMIM]HSO4 and 1-methyl benzimidazolium hydrogen sulphate [HMBIM]HSO4 were synthesized. Their physicochemical properties were investigated using spectroscopic and thermal techniques, including UV-Vis, FT-IR, 1H NMR, 13C-NMR, mass spectrometry, and TGA. The ILs were immobilized on mesoporous silica gel and characterized by FT-IR spectroscopy, scanning electron microscopy, Brunauer-Emmett-Teller analysis, ammonia temperature-programmed desorption, and thermogravimetric analysis. [HMIM]HSO4?silica and [HMBIM]HSO4?silica have been successfully applied as promising replacements for conventional catalysts for alkane isomerization reactions at room temperature. Isomerization of n-heptane and n-octane was achieved with both catalysts. In addition to promoting the isomerization of n-heptane and n-octane (a quintessential reaction for petroleum refineries), these immobilized catalysts are non-hazardous and save energy.
Production of Gasoline Fuel from Alga-Derived Botryococcene by Hydrogenolysis over Ceria-Supported Ruthenium Catalyst
Nakaji, Yosuke,Oya, Shin-Ichi,Watanabe, Hideo,Watanabe, Makoto M.,Nakagawa, Yoshinao,Tamura, Masazumi,Tomishige, Keiichi
, p. 2701 - 2708 (2017/07/28)
Hydrogenolysis of hydrogenated botryococcene (Hy-Bot) was conducted over various supported Ru catalysts, Ir/SiO2, and Pt/SiO2–Al2O3. Ru/CeO2 with very high dispersion showed the highest yield (70 %) of gasoline-range (C5–C12) alkanes at 513 K. The main gasoline-range products were dimethylalkanes. This yield is comparable to or higher than the gasoline yields from botryococcene in the literature, which were obtained at much higher temperature. Ir/SiO2 also showed a high fuel yield, but the activity was much lower than that with the Ru catalysts. The reaction over Pt/SiO2–Al2O3 slowed down before total conversion of Hy-Bot was achieved. Ru/CeO2 was stable in the hydrogenolysis of Hy-Bot without loss of activity and selectivity during reuses. The carbon balance was low for the hydrogenolysis of Hy-Bot over all catalysts if the main products are heavy hydrocarbons, whereas for the hydrogenolysis of squalane the carbon balance was kept near 100 %. 1H NMR spectra of the product mixture and thermogravimetric analyses of the product mixture and the recovered catalyst revealed that the formation of aromatic compounds, polymeric products, and coke was negligible for the carbon balance. In a model reaction using substrate compounds with a substructure of Hy-Bot, only 2,5-dimethylhexane, which has a C6 chain with two Cprimary?Ctertiary bonds, produced a cyclic product, 1,4-dimethylcyclohexane, which has a higher boiling point than the substrate. This dehydrocyclization reaction makes the product distribution in the hydrogenolysis of Hy-Bot more complex.
GAS-TO-LIQUID REACTOR AND METHOD OF USING
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Paragraph 0140-0142, (2019/08/15)
A device and a process to propagate molecular growth of hydrocarbons, either straight or branched chain structures, that naturally occur in the gas phase to a molecular size sufficient to shift the natural occurring phase to a liquid or solid state is provided. According to one embodiment, the device includes a grounded reactor vessel having a gas inlet, a liquid outlet, and an electrode within the vessel; a power supply coupled to the electrode for creating an elecirostatic field within the vessel for converting the gas to a liquid and or solid state.
IONIC LIQUID ALKYLATION OF 1-BUTENE TO PRODUCE 2,5-DIMETHYLHEXANE
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Page/Page column 17, (2015/09/23)
A process for producing dimethylhexanes (DMH) is provided. The DMH can be used to produce p-xylene. The process involves the alkylation of isobutane and 1-butene using an ionic liquid to produce naphtha that is rich in DMH. The DMH is then converted in high selectivity to xylene, including p-xylene, by dehydrocyclization.
IONIC LIQUID ALKYLATION OF 1-BUTENE TO PRODUCE 2,5-DIMETHYLHEXANE
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Paragraph 0072, (2015/08/04)
A process for producing dimethylhexanes (DMH) is provided. The DMH can be used to produce p-xylene. The process involves the alkylation of isobutane and 1-butene using an ionic liquid to produce naphtha that is rich in DMH. The DMH is then converted in high selectivity to xylene, including p-xylene, by dehydrocyclization.
Enhancement of dehydrogenation and hydride transfer by La3+ cations in zeolites during acid catalyzed alkane reactions
Schuessler, Florian,Schallmoser, Stefan,Shi, Hui,Haller, Gary L.,Ember, Erika,Lercher, Johannes A.
, p. 1743 - 1752 (2014/06/24)
La3+ cations exchanged into ultrastable zeolite Y and zeolite X promote catalytic isomerization, cracking, and alkylation of alkanes. La 3+ cations stabilize the zeolite lattices and, more importantly, polarize alkane C-H bonds to enhance the rates of all three reactions. This unique activity leads to stable cracking and isomerization of reactive alkanes, with polarizable C-H bonds with adjacent tertiary or quaternary carbon atoms below 370 K. The presence of La3+ cations also enhances the zeolite catalyzed hydride transfer rate for isobutane alkylation with 2-butene leading to high catalyst stability. Solid state MAS NMR shows that the strongest positive effects are associated with nonhydroxylated La3+ cations accessible to the reacting molecules in supercages of the zeolite. The high activity is the result of a cooperative polarization of C-H bonds of alkanes by La3+ cations and the presence of stable and strong Bronsted acid sites.
Paraffin alkylation
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Page/Page column 7, (2008/06/13)
A liquid acid process is disclosed in which a hydrocarbon component containing an olefin, an olefin precursor or mixture and an isoalkane and a liquid acid catalyst is fed to a downflow reaction zone containing a disperser, under conditions to induce pulse flow at or near the outlet to react the isoalkane and olefin to produce a reaction product and feeding the reaction product to a vaporization zone containing a disperser under conditions to induce pulse flow at or near the outlet of the vaporization zone. A pressure drop across the disperser in the vaporization zone causes partial vaporization of the hydrocarbon which quench es the heat reaction and cooling the unvaporized portion of said reaction product, which is recovered and allowed to separate into an acid phase and hydrocarbon phase containing the alkylate. The acid catalyst and hydrocarbons may be fractally fed to the reaction zone.
Alkylation process with recontacting in settler
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Page/Page column 3-5, (2008/06/13)
A system and/or process for decreasing the level of at least one organic fluoride present in a hydrocarbon phase contained in an alkylation settler by contacting the hydrocarbon phase with an HF containing stream, containing greater than about 80 wt. % and less than about 94 wt. % HF, in the intermediate portion of the settler which contains at least one tray system, with each tray system comprising a perforated tray defining a plurality of perforations and a layer of packing below the perforated tray, are disclosed.
Disproportionation of hydrocarbons
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Page 3, (2010/02/07)
A novel hydrocarbon disproportionation process is provided and includes contacting a hydrocarbon feed comprising at least one paraffin with a disproportionation catalyst comprising a support component, a metal, and a halogen in a disproportionation reaction zone under disproportionation reaction conditions.
Alkene oligomerization process
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Page 5-6, (2008/06/13)
A process for oligomerising alkenes having from 3 to 6 carbon atoms which comprises contacting a feedstock comprising a) one or several alkenes having x carbon atoms, and, b) optionally, one or several alkenes having y carbon atoms, x and y being different, with a catalyst containing a zeolite of the MFS structure type, under conditions to obtain selectively oligomeric product containing predominant amounts of certain oligomers. The process is carried out at a temperature comprised between 125 and 175° C. when the feedstock contains only alkenes with 3 carbon atoms and between 140 and 240° C., preferably between 140 and 200° C. when the feedstock contains comprises at least one alkene with 4 or more carbon atoms.
