58484-97-2Relevant academic research and scientific papers
Catalytic asymmetric sulfimidation of 1,3-dithianes
Miyake, Yoshihiro,Takada, Hiroya,Ohe, Kouichi,Uemura, Sakae
, p. 2373 - 2376 (1998)
A direct catalytic sulfimidation of 1,3-dithianes to the corresponding chiral monosulfimides with N-(p-tolylsulfonyl)imino(phenyl)iodinane (TsN=IPh) using a catalytic amount of copper(I) triflate (CuOTf) and a chiral 4,4′-disubstituted bis(oxazoline) as l
Conformational Preferences of Sulfimides
Errington, William,Sparey, Tim J.,Taylor, Paul C.
, p. 1439 - 1444 (2007/10/02)
The X-ray crystal structures of sulfimides 11, 15 and 16 are reported.Analysis of these and literature data suggests that the conformational preferences of sulfimides of six-membered cyclic sulfides can be rationalised by attractive and repulsive special gauche effects.Such effects may also affect the conformations of sulfimides of five-membered cyclic sulfides, but it is necessary, in addition, to invoke other interactions.
