58668-70-5

Upstream product

• 21143-47-5 α,α'-dioxydibenzyl alcohol 
• 87943-83-7 1-Phenyl-9,10,11-trioxa-tricyclo[6.2.1.0^2,7]undeca-2,4,6-triene 
• 77196-47-5 bis-(α-hydroxy-4-methylbenzyl) peroxide 
• 1224455-17-7 1-phenyl-2,3-dihydro-1H-indene-1,2-diol 
• 100-58-3 phenylmagnesium bromide 
• 83-33-0 inden-1-one 
• 36374-47-7 1-hydroxy 1-phenyl indane 
• 1961-97-3 3-phenyl-1H-indene 
• 73258-06-7 1,4-epoxy-4,5-dihydro-1H-2,3-benzodioxepin 
• 77116-23-5 C₁₅H₁₂Cl₅O₃Sb 
• 2407-94-5 1,1'-dihydroxycyclohexyl peroxide 
• 64655-21-6 α-hydroxydecyl hydroperoxide 

Downstream Products

• 126614-42-4 o-<(1,2,4-trioxolan-3-yl)methyl>benzophenone 
• 126614-46-8 6,7-dihydro-1-phenyl-1,6-epoxy-1H-2,3,5-benzotrioxonine 
• 2292-59-3 3,4-Dihydro-1-phenyl-1H-benzopyran 
• 56461-13-3 C₁₇H₁₆O₃ 
• 56461-08-6 4-benzoylindan-1-one 
• 56461-10-0 5-Benzoyl-3,4-dihydro-2H-naphthalen-1-one 
• 56461-02-0 2-benzoylphenylpropionic acid 
• 54996-38-2 (2-(2-hydroxyethyl)phenyl)(phenyl)methanone 
• 76355-54-9 1,1-dimethoxy-2-o-benzoylphenylethane 

Relevant academic research and scientific papers

Oxidations of alkenes with hypervalent iodine reagents: An alternative ozonolysis of phenyl substituted alkenes and allylic oxidation of unsubstituted cyclic alkenes

Unsaturated CC double bonds with a phenyl substituent can be cleaved with iodylbenzene and iodosylbenzene to give carbonyl compounds. It is believed that the reactions occur via a radical pathway. The allylic oxidation of cyclic alkenes lacking a phenyl substituent was achieved in acetonitrile/water mixture (3:1) also using iodylbenzene and iodosylbenzene.

Synthesis of substituted 4-aroyl-1-indanone and 5-aroyl-1-tetralone

Several substituted 4-aroyl-1-indanones 2 and 5-aroyl-1-tetralones 3 were prepared in good yields from 1-indanones 1 via a series of reasonable transformations.

Structure-reactivity relationships in (2-hydroxyethyl)benzophenone photoremovable protecting Groups

A detailed study of substituent effects on the photochemical conversion of esters of (2-hydroxyethyl)benzophenone to the carboxylic acid was performed with the aim of improving on the reactivity of the parent, which was first reported decades ago. Over 20

18O-tracer studies of Fe(II)-induced decomposition of 1,2,4-trioxolanes (ozonides) derived from cyclopentenes and indenes. Inner-sphere electron transfer reduction of the peroxide linkage

Fe(II)-induced decomposition of 1,2,4-trioxolanes (ozonides) 1 and 2 is studied in detail. The inner-sphere electron transfer reduction, which is sensitive to steric effects, is proposed to be a reasonable mechanism for the peroxide decomposition, i.e., the selective generation of one of the two possible Fe(III)-complexed oxy radicals. The fate of the oxy radical species is revealed in detail by using 18O-tracer studies in the reduction of 18O-labeled ozonides 1a and 2a, in which the ethereal oxygens are labeled by 18O atom (18O, 77%) and also by the reduction in the presence of H218O (18O, 10%). The results of the 18O-tracer studies are consistent with the regioselective generation of the Fe(III)-complexed oxy radical species.

Cycloaddition between Carbonyl Oxides and Dicarbonyl Compounds: Isolation and Characterization of Novel Polycyclic 1,2,4,6-Tetroxepane Derivatives

Formaldehyde O-oxide reacts with dicarbonyl compounds to produce mono-ozonides formed by conventional cycloadditions to an aldehyde carbonyl group of the substrate, and/or polycyclic 1,2,4,6-tetroxepane derivatives arising from formal cycloadditions involving both carbonyl groups.Similar reactions between the more highly substituted carbonyl oxides, benzaldehyde and octanal O-oxides, and dicarbonyl compounds yielded the corresponding mono-ozonides as the sole isolable cycloaddition products.In certain favorable cases, mono-ozonides could undergo acid-catalysed intramolecular rearrangement to the corresponding 1,2,4,6-tetroxepanes.X-Ray crystallographic analyses of two 1,2,4,6-tetroxepanes, 6a and 13b, are recorded.

Synthesis and X-Ray Analysis of 2,3,5,6,11-Pentaoxabicycloundecanes

The reactions of bicyclic ozonides and aldehyde- or ketone-derived peroxides, performed or generated in situ, in the presence of chlorosulphonic acid afford the corresponding 2,3,5,6,11-pentaoxabicycloundecanes.In addition, 1,2,4,5-tetraoxans are often isolated from the product mixture.Mechanisms are proposed to account for the observed peroxidic products.An X-ray analysis of the crystalline product (4b) confirms the general structure and reveals that it is solely the exo-isomer.

1-Azidoisochromenes. A New Route to 3,1-benzoxazepines

Nucleophilic attack of sodium azide on isochromylium salts leads to the preparation of 1-azidoisochromenes which when heated lose molecular nitrogen and give 3,1-benzoxazepines.