76355-54-9Relevant academic research and scientific papers
Reaction of Ozonides with Methanol in the Presence of Chlorosulphonic Acid: Selective Cleavage of the C-O Bond of the Peroxide Bridge
Miura, Masahiro,Nojima, Masatomo,Kusabayashi, Shigekazu
, p. 2909 - 2913 (2007/10/02)
The reaction of 1,2,4-trioxolans (ozonides) (1) with methanol in the presence of chlorosulphonic acid gives good yields of products formed via the corresponding α-methoxy hydroperoxides.The order of reactivity of the ozonides, as estimated by periodic measurement of the n.m.r. spectra of a mixture of the ozonide and chlorosulphonic acid in CD3OD, is as follows: (1a), (1b) > (1c), (1d), (1e), (1f), (1g) > (1h).
