58736-79-1

Upstream product

• 92-84-2 10H-phenothiazine 
• 137-07-5 2-amino-benzenethiol 
• 37750-29-1 2-(4-chlorophenylthio)aniline 
• 106-39-8 bromochlorobenzene 
• 637-87-6 1-Chloro-4-iodobenzene 
• 106-46-7 para-dichlorobenzene 

Downstream Products

• 1771775-13-3 10-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-10H-phenothiazine 

Relevant academic research and scientific papers

Continuous-flow electro-oxidative coupling of sulfides with activated methylene compounds leading to sulfur ylides

An unprecedentedly straightforward electro-oxidative coupling of sulfides with activated methylene compounds to synthesize sulfur ylides has been developed. Good to excellent yields can be obtained under catalyst- and oxidant-free conditions at room tempe

Transition-Metal-Free Synthesis of N-Arylphenothiazines through an N- And S-Arylation Sequence

An efficient synthetic method of N-arylphenothiazines from o-sulfanylanilines under transition-metal-free conditions is disclosed. An N- and S-arylation sequence of o-sulfanylanilines enabled us to synthesize a wide variety of N-arylphenothiazines. In par

Cavity-promotion by pillar[5]arenes expedites organic photoredox-catalysed reductive dehalogenations

The efficiency of the photo-induced electron transfer in photoredox catalysis is limited by the diffusional collision of the excited catalyst and the substrate. We herein present cavity-bound photoredox catalysts, which preassociate the substrates, leading to significantly shortened reaction times. A pillar[5]arene serves as the cavity and phenothiazine as a catalyst in the reductive dehalogenation of aliphatic bromides as a proof of concept reaction.

The same molecule but a different molecular conformation results in a different room temperature phosphorescence in phenothiazine derivatives

Room temperature phosphorescence (RTP) luminogens have attracted much attention because of their wide range of applications in chemical sensors, bio-imaging, anti-counterfeiting technology, etc. However, these luminogens are still very scarce, especially

Spiro-xanthene fluorene-cored compound and application thereof to organic electroluminescent devices

The invention discloses a spiro-xanthene fluorene-cored compound and application thereof to organic electroluminescent devices. Containing a s spiro-xanthene fluorene structure, the spiro-xanthene fluorene-cored compound is high in rigidity, and after bei

Compound with spirodimethyl anthracene fluorene as core and application thereof in organic light emission diode device

The invention relates to a compound with spirodimethyl anthracene fluorene as a core and an application thereof in organic light emission diode device. A structure of the compound is shown as the following formula. The compound provided by the invention u

Room temperature phosphorescence molecule based on phenothiazine derivative, preparation method and application thereof

The invention discloses a room temperature phosphorescence molecule based on a phenothiazine derivative, a preparation method and application thereof. The room temperature phosphorescence molecule based on the phenothiazine derivative has a structure shown as formula (I), wherein R is -OCH3, -CH3, -H, -Br, -Cl, -F or -CF3. According to the invention, mainly phenothiazine is adopted as the core, and C-N coupling reaction is carried out to connect phenothiazine with a benzene ring derivative, and then oxidation is carried out to obtain the target product. The solid powder of the compounds all have room temperature phosphorescence phenomenon, and have a longest life up to 398ms, thus being applicable as anti-counterfeit materials. And the preparation method provided by the invention has the advantages of mild reaction conditions and high yield.

Mechanism of Photoinduced Metal-Free Atom Transfer Radical Polymerization: Experimental and Computational Studies

Photoinduced metal-free atom transfer radical polymerization (ATRP) of methyl methacrylate was investigated using several phenothiazine derivatives and other related compounds as photoredox catalysts. The experiments show that all selected catalysts can b