58736-90-6Relevant academic research and scientific papers
Three polymorphs of one luminogen: How the molecular packing affects the RTP and AIE properties?
Yang, Jie,Ren, Zichun,Chen, Bin,Fang, Manman,Zhao, Zujin,Tang, Ben Zhong,Peng, Qian,Li, Zhen
, p. 9242 - 9246 (2017)
Polymorphism of organic molecules has received special attention, since the significantly different photophysical properties can provide important information to build a bridge between the micro- and macro-world. Here, we report three crystalline polymorphs of CzS-CN, which display much different properties of room temperature phosphorescence (RTP) and aggregation-induced emission (AIE). Due to their different molecular packings, the RTP lifetimes change from 266 ms to 41 ms, and then to 32 ms, accompanied by different photoluminescence quantum yields of crystals from 22.6% and 17.8% to 6.9%. Careful analyses of these crystal structures demonstrate that the properties are highly related to the packing mode and molecular configuration, regardless of the same chemical structure, thus disclosing some important clues to understand the structure-packing-property relationship of RTP and AIE performances.
Novel phenoxazine-benzonitrile and phenothiazine-benzonitrile donor-acceptor molecules with thermally activated delayed fluorescence (TADF)
Baraket, Faiza,Pedras, Bruno,Torres, érica,Brites, Maria Jo?o,Dammak, Mohamed,Berberan-Santos, Mário N.
, (2020)
Four novel TADF emitters, containing phenothiazine and phenoxazine as electron-donors and benzonitrile derivatives as electron-acceptors were synthesized and fully characterized. Their photophysical (absorption and emission spectra, molar extinction coeff
Synthesis and Biological Investigation of Phenothiazine-Based Benzhydroxamic Acids as Selective Histone Deacetylase 6 Inhibitors
V?gerl, Katharina,Ong, Nghia,Senger, Johanna,Herp, Daniel,Schmidtkunz, Karin,Marek, Martin,Müller, Martin,Bartel, Karin,Shaik, Tajith B.,Porter, Nicholas J.,Robaa, Dina,Christianson, David W.,Romier, Christophe,Sippl, Wolfgang,Jung, Manfred,Bracher, Franz
, p. 1138 - 1166 (2019)
The phenothiazine system was identified as a favorable cap group for potent and selective histone deacetylase 6 (HDAC6) inhibitors. Here, we report the preparation and systematic variation of phenothiazines and their analogues containing a benzhydroxamic acid moiety as the zinc-binding group. We evaluated their ability to selectively inhibit HDAC6 by a recombinant HDAC enzyme assay, by determining the protein acetylation levels in cells by western blotting (tubulin vs histone acetylation), and by assessing their effects on various cancer cell lines. Structure-activity relationship studies revealed that incorporation of a nitrogen atom into the phenothiazine framework results in increased potency and selectivity for HDAC6 (more than 500-fold selectivity relative to the inhibition of HDAC1, HDAC4, and HDAC8), as rationalized by molecular modeling and docking studies. The binding mode was confirmed by co-crystallization of the potent azaphenothiazine inhibitor with catalytic domain 2 from Danio rerio HDAC6.
Co-adsorbent Materials with Hole Transporting Property for Dye-Sensitized Solar Cell and Method Dye-Sensitized Solar Cell comprises the same
-
Paragraph 0051; 0093-0095, (2016/10/17)
The present invention refers to, a the hole future quality represented by compounds having formula 1, use as public absorption body thereof, and relates to solar cell including. [Formula 1]
Tailor-made hole-conducting coadsorbents for highly efficient organic dye-sensitized solar cells
Choi, In Taek,Ju, Myung Jong,Song, Sang Hyun,Kim, Sang Gyun,Cho, Dae Won,Im, Chan,Kim, Hwan Kyu
supporting information, p. 15545 - 15555 (2013/11/19)
The Y-shaped, low molecular mass, hole-conductor (HC), acidic coadsorbents 4-{3,7-bis[4-(2-ethylhexyloxy)phenyl]-10H-phenothiazin-10-yl}benzoic acid (PTZ1) and 4-{3,7-bis[4-(2-ethylhexyloxy)phenyl]-10H-phenothiazin-10-yl}biphenyl-4- carboxylic acid (PTZ2)
Synthesis, optical, and electroluminescent properties of alternating copolymer based on phenothiazine and fluorene with oxadiazole pendant
Park, Young Sue,Choi, Jiyoung,Kim, Donghan,Lee, Bong,Suh, Hongsuk,Kim, Joo Hyun
experimental part, p. 294 - 303 (2012/05/04)
A new alternating copolymer based on phenothiazine-fluorene with aromatic 1,3,4-oxadiazole (OXD) as a side chain (poly(10-{4-[5-(4-tert-butyl-phenyl)- [1,3,4]oxadiazol-2-yl]-phenyl}-phenothiazine-3,7-diyl-alt-9,9-dihexyl-2, 7-fluorene, PTOXDPF) was synthe
Nature of the lowest triplet states of 4'-substituted N-phenylphenothiazine derivatives
Borowicz,Herbich,Kapturkiewicz,Anulewicz-Ostrowska,Nowacki,Grampp
, p. 4275 - 4280 (2007/10/03)
The nature of the lowest triplet state of the donor-acceptor N-phenylphenothiazine derivatives has been studied by means of phosphorescence and EPR spectroscopy in various low temperature glasses. The triplet excitation of N-phenylphenothiazine and N-(p-a
