5895-68-1

Basic information

• Product Name: bis[bis(4-methylphenyl)methylidene]hydrazine
• Synonyms: Bis(di-p-tolylmethylene)hydrazine
• CAS NO: 5895-68-1
• Molecular Formula: C₃₀H₂₈N₂
• Molecular Weight: 416.5567
• Mol File: 5895-68-1.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 528.6°C at 760 mmHg
• Flash Point: 266.6°C
• Density: 1.02g/cm³
• Vapor Pressure: 9.94E-11mmHg at 25°C
• Refractive Index: 1.582
• CAS DataBase Reference: bis[bis(4-methylphenyl)methylidene]hydrazine(CAS DataBase Reference)
• NIST Chemistry Reference: bis[bis(4-methylphenyl)methylidene]hydrazine(5895-68-1)
• EPA Substance Registry System: bis[bis(4-methylphenyl)methylidene]hydrazine(5895-68-1)

Safety Data

• Hazardous Substances Data: 5895-68-1(Hazardous Substances Data)

Upstream product

• 38061-80-2 2,2-dimethyl-5,5-di-p-tolyl-2,5-dihydro-[1,3,4]thiadiazole 1-oxide 
• 1143-91-5 bis(4-methylphenyl)diazomethane 
• 4358-64-9 cis-1,4-anhydroerythritol 
• 24686-79-1 4,4'-dimethyl-thiobenzophenone S-oxide 
• 55816-25-6 bis(4-methylphenyl)methanone hydrazone 
• 4148-58-7 (4aR,6S,7S,8R,8aS)-6-Methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol 
• 104-85-8 para-methylbenzonitrile 
• 4294-57-9 para-methylphenylmagnesium bromide 
• 60-29-7 diethyl ether 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 71-43-2 benzene 

Downstream Products

• 77408-53-8 Di-p-tolylmethyl-carbamic acid ethyl ester 

Relevant articles and documents

An Adaptable Chelating Diphosphine Ligand for the Stabilization of Palladium and Platinum Carbenes

Group 10 metal carbenes are proposed in catalytic transformations; however, their isolation remains difficult without the presence of a heteroatom donor. The adaptable cis and trans coordinating ligand PterP (1,2-bis(2-(diisopropylphosphino)phe

Synthesis of 1, 1, 4, 4-tetraryl-1, 3-diazabutadienes by oxidation of hydrazones using bis(acetylacetonato)copper (II)

The treatment of benzophenone hydrazones with bis(acetylacetonato)copper(II) affords 1, 1, 4, 4-tetraryl-1, 3-diaza-butadienes in good yields. The formation of diazabutadienes is explained by the intermediacy of carbenoids generated by the Cu(acac)2

Electrochemical Oxidation of Benzophenone Hydrazones

The anodic oxidation of benzophenone hydrazones (1) was found to give several products, depending upon the electrolysis conditions employed such as electrode material, temperature, and electrolyte composition.For example, the oxidation using a platinum anode at room temperature in LiClO4-MeCN afforded exclusively benzophenone azines (2), whereas in NaOMe-MeOH benzophenone dimethyl acetals (3) were formed as the main products.On the other hand, the oxidation using a graphite anode in refluxing MeOH containing NaOMe gave diphenylmethyl methyl ethers (4), along with diphenylmethanes (5).When the analogous electrolysis was conducted in the presence of methacrylic acid derivatives, corresponding diphenylcyclopropanes (7) were obtained in relatively high yields.