59034-18-3

Upstream product

• 74056-04-5 2-(3-bromopropyl)-2-cyclohexen-1-one 
• 121196-18-7 1-(1,3-dioxolan-2-yl)octan-4-one N,N-dimethylhydrazone 
• 120596-59-0 cis-2-(3-phenylselenopropyl)-3-tributylstannylcyclohexanone 
• 591-78-6 n-hexan-2-one 
• 112547-28-1 2-hexanone N,N-dimethylhydrazone 
• 120596-59-0 C₆H₈(O)(Sn(C₄H₉)3)(CH₂)3SeC₆H₅ 
• 33948-36-6 2-iodocyclohex-2-en-1-one 
• 927-77-5 n-propylmagnesium bromide 
• 930-68-7 cyclohexenone 
• 628-91-1 di-n-propyl zinc 

Downstream Products

• 113088-71-4 3-Chloro-2-propyl-cyclohex-2-enol 
• 113088-67-8 2-Chloro-3-propyl-cyclohexa-1,3-dienecarbaldehyde 
• 59034-20-7 2-propyl-cyclohex-2-enone-(2,4-dinitro-phenylhydrazone) 

Relevant academic research and scientific papers

Versatile CuI/Pd0 dual catalysis for the synthesis of quaternary α-allylated carbonyl compounds: Development, mechanistic investigations and scope

We report herein a versatile cooperative dual catalysis reaction based on a CuI/Pd0 system. Mechanistic investigation shows that every component plays a crucial role in determining the reaction outcome. The reaction is successfully extended to various substrates; such as α,β-unsaturated ketones, malonates and coumarins. The strategy tolerates different substitution patterns and affords good yields for each family of substrates.

Copper/palladium-catalyzed 1,4 reduction and asymmetric allylic alkylation of α,β-unsaturated ketones: Enantioselective dual catalysis

Cooperative efforts: The catalytic coupling of the two organometallic intermediates is possible through a Cu/Pd-based dual catalysis (see scheme; LG=leaving group), in which the CuI catalytic cycle generates catalytically the starting material

CARBOCYCLIC RING EXPANSION REACTIONS VIA RADICAL CHAIN PROCESSES

A free radical mediated ring expansion of cis- and trans-α-alkylated-β-stannylcyclohexanones to provide efficient routes to cis- and trans-cyclononenones and cyclodecenones is described.The cis-/trans- relationship in the precursor was found to have signi

Carbocyclic Ring Expansion Reactions via Radical Chain Processes

Free radical mediated ring expansion of cis- and trans-α-substituted-β-stannylcyclohexanones provides efficient routes to cis- and trans-cyclononenones and cyclodecenones; the cis-/trans-geometry of the precursor controls the alkene geometry of the ring-e

A Three-Step Pyridoannelation of Carbonyl Compounds

The elaboration of a pyridine nucleus onto an α-methylene carbonyl compound can be accomplished through a three step reaction sequence based on the regiospecific alkylation of N,N-dimethylhydrazones with bromoethyl-1,3-dioxolane.Scope and limitations of the new method are considered.