59045-84-0Relevant academic research and scientific papers
Oxyonium phosphobetaines - Unusually stable nucleophilic catalyst-phosphate complexes formed from H-phosphonates and N-oxides
Materna, Magdalena,Stawinski, Jacek,Kiliszek, Agnieszka,Rypniewski, Wojciech,Sobkowski, Michal
, p. 14448 - 14451 (2016/02/19)
Aryl H-phosphonates react with N-oxides to form previously unknown stable zwitterionic oxyonium phosphates comprising an -O-P-O-N+Z atom system. Their structures were confirmed i.e. by X-ray crystal structure analysis, and some mechanisms were proposed for their formation. Stability during storage and reactivity toward nucleophiles points to their possible synthetic applications.
