59051-65-9Relevant academic research and scientific papers
FUNCTIONALIZATION OF SATURATED HYDROCARBONS IN THE PRESENCE OF APROTIC ORGANIC SUPERACIDS. 2. SINGLE-STAGE SYNTHESIS OF THIOESTERS R1CO-SR FROM n-ALKANES OR CYCLOALKANES (RH), ELEMENTAL SULFUR, AND COMPLEXES R1COBr*2AlBr3
Orlinkov, A. V.,Akhrem, I. S.,Afanas'eva, L. V.,Vitt, S. V.,Vol'pin, M. E.
, p. 90 - 92 (1991)
It has been found for the first time that n-alkanes and cycloalkanes (RH) can interact with elemental sulfur at ca. 20 deg C.These reactions go forward in the presence of aprotic organic superacids with the composition R1CO-SR in satisfactory yields.
THE FACILE AND EFFICIENT PREPARATION OF PHENOLIC AND THIOL ESTERS
Dellaria, Joseph F.,Nordeen, Carl,Swett, Leo R.
, p. 1043 - 1048 (2007/10/02)
Phenolic and thiol esters are prepared efficiently in a facile process which involves heating the desired acyl halide and thiol or phenol as a neat mixture.Distillation after HX (X = Cl or Br) gas evolution ceases provides the title compounds in 75-96percent yields.
