FUNCTIONALIZATION OF SATURATED HYDROCARBONS IN THE PRESENCE OF APROTIC ORGANIC SUPERACIDS. 2. SINGLE-STAGE SYNTHESIS OF THIOESTERS R1CO-SR FROM n-ALKANES OR CYCLOALKANES (RH), ELEMENTAL SULFUR, AND COMPLEXES R1COBr*2AlBr3

DOI: 10.1007/BF00959637

Source and publish data:

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 90 - 92 (1991)

Update date:2022-08-05

Topics:

Authors:

Orlinkov, A. V.

Akhrem, I. S.

Afanas'eva, L. V.

Vitt, S. V.

Vol'pin, M. E.

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Article abstract of DOI:10.1007/BF00959637

It has been found for the first time that n-alkanes and cycloalkanes (RH) can interact with elemental sulfur at ca. 20 deg C.These reactions go forward in the presence of aprotic organic superacids with the composition R¹CO-SR in satisfactory yields.

Full text of DOI:10.1007/BF00959637

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