59057-95-3

Upstream product

• 86049-40-3 2-benzyloxymethyl-5-hydroxymethyl-2,5-dimethoxy-2,5-dihydrofuran 
• 86049-38-9 5-((benzyloxy)methyl)-furan-2-carbaldehyde 
• 86049-39-0 (5-((benzyloxy)methyl)furan-2-yl)methanol 
• 100-44-7 benzyl chloride 
• 16361-14-1 2-benzyloxymethylfuran 
• 98-00-0 (2-furyl)methyl alcohol 
• 59057-90-8 1-O-benzyl-3,4-dideoxy-D,L-hex-3-en-2-ulopyranos-5-ulose 
• 149-73-5 trimethyl orthoformate 
• 74-88-4 methyl iodide 

Downstream Products

• 131262-60-7 4-Benzyloxymethyl-5-hydroxy-4-methoxy-2-cyclopenten-1-one 
• 62130-92-1 methyl 1-O-benzyl-3,4-dideoxy-α-D,L-glycero-hex-3-en-2-ulopyranoside 
• 62130-92-1 methyl 1-O-benzyl-3,4-dideoxy-β-D,L-glycero-hex-3-en-2-ulopyranoside 
• 86049-59-4 methyl 1-O-benzyl-α-D,L-erythro-hex-2-ulopyranosid-5-ulose 
• 86049-54-9 methyl 3,4,5-tri-O-acetyl-1-O-benzyl-α-D,L-tagatopyranoside 
• 86049-54-9 methyl 3,4,5-tri-O-acetyl-1-O-benzyl-β-D,L-fructopyranoside 
• 86049-54-9 methyl 3,4,5-tri-O-acetyl-1-O-benzyl-α-D,L-sorbopyranoside 
• 86049-47-0 methyl 5-O-acetyl-3,4-anhydro-1-O-benzyl-β-D,L-ribo-hex-2-ulopyranoside 
• 86049-47-0 methyl 5-O-acetyl-3,4-anhydro-1-O-benzyl-β-D,L-lyxo-hex-2-ulopyranoside 
• 86049-47-0 methyl 5-O-acetyl-3,4-anhydro-1-O-benzyl-α-D,L-ribo-hex-2-ulopyranoside 
• 86049-46-9 methyl 3,4-anhydro-1-O-benzyl-β-D,L-ribo-hex-2-ulopyranoside 
• 86049-46-9 (1R,2S,5S,6R)-2-Benzyloxymethyl-2-methoxy-3,7-dioxa-bicyclo[4.1.0]heptan-5-ol 
• 86049-46-9 methyl 3,4-anhydro-1-O-benzyl-α-D,L-ribo-hex-2-ulopyranoside 
• 86049-61-8 (1S,5R,6S,12R)-12-Benzyloxymethyl-12-methoxy-3,3,8,8-tetramethyl-2,4,7,9,11-pentaoxa-tricyclo[4.3.3.0^1,5]dodecane 

Relevant academic research and scientific papers

STEREOSPECIFIC SYNTHESIS OF METHYL D,L-HEX-2-ULOPYRANOSIDES FROM FURAN COMPOUNDS

2-Benzyloxymethyl-5-hydroxymethylfuran was converted, according to the known method, into methyl 1-O-benzyl-3,4-dideoxy-D,L-hex-3-en-2-ulopyranos-5-ulose.Reduction of the latter and hydroxylation or epoxidation, followed by the oxirane ring opening, afforded the title compounds with α-sorbo-, β-fructo-, α-tagato- and α-psico- configuration.The steric course of reduction, hydroxylation and epoxidation reactions were examined.