86049-46-9

Upstream product

• 59057-90-8 1-O-benzyl-3,4-dideoxy-D,L-hex-3-en-2-ulopyranos-5-ulose 
• 59057-95-3 methyl 1-O-benzyl-3,4-dideoxy-D,L-hex-3-en-2-ulopyranosid-5-ulose 
• 62130-95-4 methyl 5-O-benzoyl-1-O-benzyl-3,4-dideoxy-β-D,L-glycero-hex-3-en-2-ulopyranoside 
• 86049-51-6 methyl 3,4-anhydro-5-O-benzoyl-1-O-benzyl-β-D,L-lyxo-hex-2-ulopyranoside 
• 86049-42-5 methyl 5-O-acetyl-1-O-benzyl-3,4-dideoxy-D,L-glycero-hex-3-en-2-ulopyranoside α 
• 62130-92-1 methyl 1-O-benzyl-3,4-dideoxy-α-D,L-glycero-hex-3-en-2-ulopyranoside 
• 86049-40-3 2-benzyloxymethyl-5-hydroxymethyl-2,5-dimethoxy-2,5-dihydrofuran 
• 86049-38-9 5-((benzyloxy)methyl)-furan-2-carbaldehyde 
• 86049-39-0 (5-((benzyloxy)methyl)furan-2-yl)methanol 
• 100-44-7 benzyl chloride 
• 16361-14-1 2-benzyloxymethylfuran 
• 98-00-0 (2-furyl)methyl alcohol 
• 62130-92-1 methyl 1-O-benzyl-3,4-dideoxy-β-D,L-glycero-hex-3-en-2-ulopyranoside 

Downstream Products

• 86049-47-0 methyl 5-O-acetyl-3,4-anhydro-1-O-benzyl-β-D,L-ribo-hex-2-ulopyranoside 
• 86049-54-9 methyl 3,4,5-tri-O-acetyl-1-O-benzyl-β-D,L-fructopyranoside 
• 86049-47-0 methyl 5-O-acetyl-3,4-anhydro-1-O-benzyl-β-D,L-lyxo-hex-2-ulopyranoside 
• 86049-54-9 methyl 3,4,5-tri-O-acetyl-1-O-benzyl-α-D,L-sorbopyranoside 
• 86049-47-0 methyl 5-O-acetyl-3,4-anhydro-1-O-benzyl-α-D,L-ribo-hex-2-ulopyranoside 

Relevant academic research and scientific papers

STEREOSPECIFIC SYNTHESIS OF METHYL D,L-HEX-2-ULOPYRANOSIDES FROM FURAN COMPOUNDS

2-Benzyloxymethyl-5-hydroxymethylfuran was converted, according to the known method, into methyl 1-O-benzyl-3,4-dideoxy-D,L-hex-3-en-2-ulopyranos-5-ulose.Reduction of the latter and hydroxylation or epoxidation, followed by the oxirane ring opening, afforded the title compounds with α-sorbo-, β-fructo-, α-tagato- and α-psico- configuration.The steric course of reduction, hydroxylation and epoxidation reactions were examined.