59070-02-9Relevant academic research and scientific papers
A short, convenient synthesis of 2-arylglycidates via aryl-grignard addition to an α-bromopyruvate
Jung, Michael E.,Mengel, Werner,Newton, Trevor W.
, p. 3659 - 3666 (1999)
A simple procedure has been developed for the preparation of a series of 2-arylglycidates required for herbicidal evaluation. Treatment of the α- bromopyruvate 5 with various aryl Grignard reagents at low temperature gave directly the glycidates 4. Saponification of these then afforded the desired sodium salts 7.
