59276-36-7Relevant academic research and scientific papers
Intramolecular Heck cyclization to the galanthamine-type alkaloids: Total synthesis of (±)-lycoramine
Liang, Pi-Hui,Liu, Jing-Ping,Hsin, Ling-Wei,Cheng, Chen-Yu
, p. 11655 - 11660 (2007/10/03)
A novel approach towards the construction of the galanthamine skeleton was demonstrated by the total synthesis of (±)-lycoramine. The key steps include a Pd-catalyzed intramolecular cyclization to form the seven-membered azepane ring and a spontaneous int
Oxidation of o-Methoxyphenols with a Hypervalent Iodine Reagent: Improved Synthesis of Asatone and Demethoxyasatone
Kuerti, Laszlo,Szilagyi, Laszlo,Antus, Sandor,Nogradi, Mihaly
, p. 2579 - 2582 (2007/10/03)
Oxidation of the 2-methoxyphenols 1c-f with phenyliodonium(III) diacetate (PIDA) in methanol resulted in the formation of the cyclohexa-2,4-dienones 4c-f, which dimerized spontaneously to a single product (5c-f) in each case. Using this method the synthes
