151726-42-0Relevant articles and documents
Enantioselective Synthesis and Racemization of (?)-Sinoracutine
Volpin, Giulio,Vep?ek, Nynke A.,Bellan, Andreas B.,Trauner, Dirk
, p. 897 - 901 (2017)
Sinoracutine is a recently isolated alkaloid with unusual stereochemical and biological properties. It features an unprecedented tetracyclic 6/6/5/5 skeleton that bears an N-methylpyrrolidine ring fused to a cyclopentenone. Interestingly, both enantiomers
Intramolecular Heck cyclization to the galanthamine-type alkaloids: Total synthesis of (±)-lycoramine
Liang, Pi-Hui,Liu, Jing-Ping,Hsin, Ling-Wei,Cheng, Chen-Yu
, p. 11655 - 11660 (2007/10/03)
A novel approach towards the construction of the galanthamine skeleton was demonstrated by the total synthesis of (±)-lycoramine. The key steps include a Pd-catalyzed intramolecular cyclization to form the seven-membered azepane ring and a spontaneous int