59277-04-2

Upstream product

• 100-14-1 4-nitrobenzyl chloride 
• 88-74-4 2-nitro-aniline 
• 555-16-8 4-nitrobenzaldehdye 
• 7409-30-5 p-nitrobenzylamine 
• 1493-27-2 ortho-nitrofluorobenzene 
• 49854-41-3 4-Methyl-N-(4-nitro-benzyl)-N-(2-nitro-phenyl)-benzenesulfonamide 

Downstream Products

• 59277-08-6 acetic acid-[2-nitro-N-(4-nitro-benzyl)-anilide] 
• 59277-07-5 N-(4-Nitro-benzyl)-N-(2-nitro-phenyl)-benzamide 
• 7288-53-1 N-p-nitrobenzyl-o-phenylenediamine 
• 729-13-5 2-(4-nitrophenyl)benzimidazole 
• 95711-95-8 N,2,4,6-Tetranitro-N-(4-nitrobenzyl)-anilin 
• 954232-53-2 4-bromo-2-nitro-N-(4-nitro-benzyl)-aniline 

Relevant academic research and scientific papers

CuBr-Catalyzed Oxidation/Coupling: An Efficient and Applicable Strategy for the Synthesis of 2-Aryl Benzimidazoles from 1-Fluoro-2-nitrobenzene and Benzylamines

A novel and efficient route has been developed for the synthesis of benzimidazole derivatives via ligand-free CuBr-catalyzed oxidation and cyclization of 1,2-diamines derived from 1-fluoro-2-nitrobenzene and different arylamines as starting materials. GRAPHICAL ABSTRACT.

Palladium-catalyzed N-heteroannulation of N-allyl- or N-benzyl-2-nitrobenzenamines: synthesis of 2-substituted benzimidazoles

A palladium-catalyzed reductive N-heteroannulation of N-allyl- or N-benzyl-2-nitrobenzenamines, using carbon monoxide as the ultimate reducing agent, affording 2-substituted benzimidazoles has been developed.