59283-75-9Relevant academic research and scientific papers
Reductive transformation of bound trinitrophenyl residues and free TNT during a bioremediation process analyzed by immunoassay
Achtnich, Christof,Pfortner, Peter,Weller, Michael G.,Niessner, Reinhard,Lenke, Hiltrud,Knackmuss, Hans-Joachim
, p. 3421 - 3426 (1999)
To follow the fate of bound metabolites of TNT in soil, a synthetic trinitrophenyl residue covalently linked to humic acids was used as model compound. A selective monoclonal antibody was able to detect chemical changes of the nitro groups of the bound re
Enzymatic Reduction of 2,4,6-Trinitrotoluene and Related Nitroarenes: Kinetics Linked to One-Electron Redox Potentials
Riefler, R. Guy,Smets, Barth F.
, p. 3900 - 3906 (2000)
At military bases and munitions factories 2,4,6-trinitrotoluene (TNT) is a common soil and groundwater contaminant. Although the reduction of nitro groups in TNT and related nitroarenes has been extensively investigated, few researchers have studied the l
A comparative study of the structure, energetic performance and stability of nitro-NNO-azoxy substituted explosives
Wang, Yuan,Li, Shenghua,Li, Yuchuan,Zhang, Rubo,Wang, Dong,Pang, Siping
, p. 20806 - 20813 (2015/02/19)
2,4-Dinitro-NNO-azoxytoluene and 2,6-dinitro-4-nitro-NNO-azoxytoluene were synthesized as energetic compounds. Their structures and properties were studied by X-ray diffractometry, nuclear magnetic resonance and infrared spectroscopy. The differences betw
OYE flavoprotein reductases initiate the condensation of TNT-derived intermediates to secondary diarylamines and nitrite
Wittich, Rolf-Michael,Haidour, Ali,Van Dillewijn, Pieter,Ramos, Juan-Luis
, p. 734 - 739 (2008/09/16)
Polynitroaromatic explosives such as 2,4,6-trinitrophenol (picric acid) and 2,4,6-trinitrotoluene (TNT) are toxic and recalcitrant environmental pollutants. They persist in the environment due to the highly inactivated π system of their aromatic rings, wh
ANALYTE DETECTION
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, (2008/12/08)
The present invention relates to sensitive SE(R)RS based methods for detecting analytes such as explosives and drugs, which may be present in a sample at extremely low levels. The methods may be generally carried out in situ employing novel chemistry whic
Crystal structure and geometry-optimization study of 4-methyl-3′,5′-dinitro-4′-methyl benzylidene aniline
Yu, Wei,Yang, Li,Zhang, Tong-lai,Zhang, Jian-guo,Ren, Fu-jian,Liu, Yan-hong,Wu, Rui-feng,Guo, Jin-yu
, p. 255 - 260 (2007/10/03)
Schiff base 4-methyl-3′,5′-dinitro-4′-methyl benzylidene aniline was synthesized by the condensation of 4-amino-2,6-dinitrotoluene with 4-methylbenzaldehyde. The crystal of the title compound was obtained and it was characterized by X-ray single crystal d
Bamberger rearrangement during TNT metabolism by Clostridium acetobutylicum
Hughes,Wang,Yesland,Richardson,Bhadra,Bennett,Rudolph
, p. 494 - 500 (2007/10/03)
Studies were conducted to isolate and identify polar and oxygen- sensitive intermediates of 2,4,6-trinitrotoluene (TNT) transformation by Clostridium acetobutylicum. Studies conducted in anaerobic cell extracts demonstrated that a polar product formed fro
New method for preparing pentanitroaniline and triaminotrinitrobenzenes from trinitrotoluene
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, (2008/06/13)
Trinitrotoluene is selectively reduced by reaction with H2 S in p-dine to produce 4-amino-2,6-dinitrotoluene. This latter compound is then nitrated with HNO3 in H2 SO4 to produce pentanitroaniline which is, in
