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5934-69-0

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5934-69-0 Usage

General Description

(Z)-2-diazonio-1-tricyclo[3.3.1.1~3,7~]dec-1-ylethenolate is a chemical compound with a complex and unique structure. It contains a tricyclo[3.3.1.1~3,7~]dec-1-yl group, a diazonium ion, and an ethenolate group. (Z)-2-diazonio-1-tricyclo[3.3.1.1~3,7~]dec-1-ylethenolate is a highly reactive and unstable species due to the presence of the diazonium group, which is known for its tendency to undergo decomposition and reaction with various nucleophiles. The tricyclo[3.3.1.1~3,7~]decane framework contributes to the overall stability of the compound and may influence its reactivity. While no specific uses or applications for this compound were found in the available literature, its unique structure and reactivity make it an interesting target for further study in the field of organic chemistry.

Check Digit Verification of cas no

The CAS Registry Mumber 5934-69-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 5,9,3 and 4 respectively; the second part has 2 digits, 6 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 5934-69:
(6*5)+(5*9)+(4*3)+(3*4)+(2*6)+(1*9)=120
120 % 10 = 0
So 5934-69-0 is a valid CAS Registry Number.

5934-69-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name (Z)-1-(1-adamantyl)-2-diazonioethenolate

1.2 Other means of identification

Product number -
Other names 1-Adamantacoyldiazomethane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:5934-69-0 SDS

5934-69-0Relevant articles and documents

α-Xanthylmethyl Ketones from α-Diazo ketones

López-Mendoza, Pedro,Miranda, Luis D.

, p. 3777 - 3790 (2021/07/07)

A simple and efficient method to obtain α-xanthylmethyl ketones from α-diazo ketones is described. The reaction proceeds through a protonation/nucleophilic substitution sequence in the presence of p -toluenesulfonic acid and potassium ethyl xanthogenate as the nucleophile. As α-diazo ketones can be readily synthesized from ubiquitous carboxylic acids, a broad variety of xanthates can be obtained, including examples from naturally occurring substrates.

New synthetic technology for the synthesis of hindered α-diazoketones via acyl mesylates

Nicolaou,Baran, Phil S.,Zhong, Yong-Li,Choi, Ha-Soon,Fong, Kin Chiu,He, Yun,Yoon, Won Hyung

, p. 883 - 886 (2008/02/09)

(equation presented) A mild and reliable one-pot protocol for the elaboration of sterically demanding carboxylic acids into α-diazoketones via acyl mesylates has been developed. Aside from delineating the reaction parameters which render this strategy quite general for hindered carboxylic acids, we have directly proven the existence of the fleeting acyl mesylate group as the reactive species in these reactions and shed light onto the differing mechanisms which are operative in the activation of hindered and simple carboxylic acids with methanesulfonyl chloride.

WOLFF RAERRANGEMENT OF (1-DIAZO-2-OXOALKYL) SILANES

Brueckmann, Ralf,Schneider, Klaus,Maas, Gerhardt

, p. 5517 - 5530 (2007/10/02)

Photochemical decomposition of (1-diazo-2-oxoalkyl) silanes 6a-l results in Wolff rearrangement yielding silyl ketenes 8a-l.From (1-diazo-3,3-dimethyl-2-oxobutyl) silanes 6c-f, 2-silyl-cyclobutanones 9c-f are formed as by-products, arising from intramolecular C/H insertion of the acyl carbene intermediate.Irradiation of diazo-triisopropylsilyl-acetamide 6m yields only β-lactam 16 and γ-lactam 17.Wolff rearrangement also takes place on copper triflate catalyzed decomposition of 6a,c,l, whereas the 1-oxa-2-sila-4-cyclopentene 19 is obtained from 6f, probably as the result of SiC/H insertion of a copper carbene intermediate.

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