59467-03-7

Upstream product

• 3724-55-8 methyl but-3-enoate 
• 766-77-8 Dimethylphenylsilane 
• 14273-85-9 methyl 4-iodobutanoate 
• 59467-01-5 4-(Dimethyl-phenyl-silyl)-buttersaeure 
• 2632-95-3 γ-chloropropyldimethylphenylsilane 
• 59467-02-6 4-(Dimethyl-phenyl-silyl)-butyrylchlorid 
• 124-41-4 sodium methylate 

Relevant academic research and scientific papers

A Highly Chemoselective Cobalt Catalyst for the Hydrosilylation of Alkenes using Tertiary Silanes and Hydrosiloxanes

The hydrosilylation of alkene substrates bearing additional functionalities is difficult to achieve using earth-abundant catalysts and has not been extensively realized with both earth-abundant transition metals and tertiary silanes or hydrosiloxanes. Reported herein is a well-defined bis(carbene) cobalt(I)-dinitrogen complex for the efficient, catalytic anti-Markovnikov hydrosilylation of terminal alkenes, featuring a broad substrate scope. Alkenes containing hydroxyl, amino, ester, epoxide, ketone, formyl, and nitrile groups are selectively hydrosilylated in this reaction sequence. Multinuclear NMR studies of reactive intermediates gave insights into the mechanism.

Direct synthesis of alkylsilanes by platinum-catalyzed coupling of hydrosilanes and iodoalkanes

Alkyl iodides and tertiary silanes were successfully coupled with good functional group tolerance using a Pt(P(tBu)3)2/(iPr) 2EtN/CH3CN system. The utility of the methodology is demonstrated by the synthesis of silafluofen, a Si-containing insecticide. This journal is The Royal Society of Chemistry.