595559-92-5

Upstream product

• 192211-53-3 N-benzyl-2,3,5-tri-O-benzyl-L-xylofuranosylamine 
• 440104-33-6 (2S,3R,4R,5R)-5-benzylamino-1,3,4-O-tribenzyl-6-vinyl-1,2,3,4-hexanetetraol 
• 16838-89-4 2,3,5-tri-O-benzyl-L-xylofuranose 
• 41546-31-0 L-xylose 
• 100-39-0 benzyl bromide 
• 440104-37-0 (2R,3R,4R,5R)-N-benzyl-3,4-dibenzyloxy-5-benzyloxymethyl-2-(2-propenyl)pyrrolidine 
• 100-46-9 benzylamine 
• 169736-18-9 (2S,3R,4S)-3,4-bis(benzyloxy)-2-[(benzyloxy)methyl]-5-methoxyoxolane 
• 13039-67-3 (2S,3S,4S)-2-(hydroxymethyl)-5-methoxyoxolane-3,4-diol 

Relevant academic research and scientific papers

Synthesis of 6-deoxy-homoDMDP and its C(5)-epimer: Absolute stereochemistry of natural products from Hyacinthus orientalis

A concise enantioselective synthesis of 2,5-imino-2,5,6-trideoxy-D-manno-heptitol (6-deoxy-homoDMDP) and 2,5-imino-2,5,6-trideoxy-L-gulo-heptitol has been achieved. These compounds were used as stereochemical references to establish the absolute configuration of the corresponding naturally occurring stereoisomers, recently isolated from Hyacinthus orientalis.