595585-52-7Relevant academic research and scientific papers
Cobalt(I)-catalyzed Diels-Alder, 1,4-hydrovinylation and 1,4-hydrosilylation reactions of non-activated starting materials on a large scale
Hilt, Gerhard,Lueers, Steffen,Schmidt, Frank
, p. 634 - 638 (2004)
The transformation of non-activated starting materials with a readily accessible and easy to handle catalyst system under ambient reaction conditions is of great value for the chemo- and regioselective generation of interesting building blocks in organic
Dihydroaromatic boronic esters as building blocks for the synthesis of phenanthrenes and phenanthridines
Hilt, Gerhard,Hess, Wilfried,Schmidt, Frank
, p. 2526 - 2533 (2007/10/03)
Alkenyl-substituted dihydroaromatic boronic esters, generated by neutral cobalt(I)-catalysed Diels-Alder reactions, reacted under palladium catalysis conditions with diiodobenzene, bromoiodobenzene and iodoaniline derivatives for the synthesis of regioselectively substituted phenanthrene and phenanthridine derivatives. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005.
A two-step reaction sequence for the syntheses of tetrahydronaphthalenes
Hilt, Gerhard,Lueers, Steffen,Smolko, Konstantin I.
, p. 251 - 253 (2007/10/03)
(Chemical Equation Presented) A cobalt(I)-catalyzed Diels-Alder reaction of a boron-functionalized enyne is the key step in a two-step reaction cascade interconnecting four simple starting materials to obtain polycyclic multifunctionalized products in goo
Alkynylboronic esters as efficient dienophiles in cobalt-catalyzed Diels-Alder reactions
Hilt, Gerhard,Smolko, Konstantin I.
, p. 2795 - 2797 (2007/10/03)
Versatile building blocks with a dihydroaromatic vinylic boron substructure can be generated efficiently by cobalt-catalyzed Diels-Alder reactions and used in Suzuki coupling reactions for the synthesis of functionalized polycyclic compounds (see scheme).
