5958-53-2

Usage

Common use

Ligand in organometallic chemistry and catalysis

Physical state

Colorless liquid at room temperature

Molecular weight

468.73 g/mol

Coordination abilities

Strong, useful in the synthesis of various coordination compounds and metal complexes

Thermal stability

High, suitable for chemical reactions requiring airand moisture-sensitive conditions

Resistance

To air and moisture, making it a valuable reagent in sensitive chemical reactions

Upstream product

• 693-03-8 n-butyl magnesium bromide 
• 13904-54-6 Tetrabutyldiphosphin 
• 109-65-9 1-bromo-butane 
• 109-72-8 n-butyllithium 
• 3982-91-0 trichlorothiophosphine 
• 29942-34-5 dibutyl-diethylamino-phosphine 
• 4323-64-2 (dibutyl)chlorophosphine 

Downstream Products

• 1732-72-5 di-n-butylphosphine 
• 13904-54-6 Tetrabutyldiphosphin 
• 55656-88-7 di-n-butylthioxophosphoranyl bromide 

Relevant academic research and scientific papers

Preparation method of phosphinate, phosphinate and non-aqueous electrolyte

The present invention provides a method for preparing phosphinate, the phosphinate and a non-aqueous electrolyte. The method for preparing the phosphinate comprises the following steps: (1) reaction of Grignard reagent R1MgX with thiophosphoryl halide X3P=S in a solvent to obtain a first intermediate; (2) reaction of halogenating agent M' Xa and the first intermediate to obtian a second intermediate; and (3) reaction of the second intermediate with R2OH and water to obtain the phosphinate; wherein R1 and R2 are each selected from the group consisting of hydrocarbon groups or an organic group containing at least one element of boron, silicon, nitrogen, phosphorus, oxygen, sulfur, fluorine, chlorine, bromine, and iodine; X represents a halogen; M' represents a metal element; and a representsa valence of the metal element M'. The electrolyte prepared by from the phosphinate can improve the high-temperature cycle stability of a secondary battery, also has non-flammable, flame-retardant orself-extinguishing characteristics, and can improve the safety performance of the secondary battery.

Ferrocenyl-phosphonium ionic liquids-synthesis, characterisation and electrochemistry

New unsymmetrically substituted ferrocenyl-phosphonium ionic liquids (ILs) [FcPR2R′]NTf25a-j are synthesized by two or three step syntheses starting from ferrocene, Fc = (C5H5) Fe(C5H4); R = Me, nBu, nHex, Ph; R′ = Me, nPr, nBu, Ph; NTf2 = N(SO 2CF3)2. The selective synthesis of alkyl phosphines FcPR2via a Friedel-Crafts phosphorylation is highlighted as an alternative for the standard protocol commonly used for ferrocenyl arylphosphines involving lithiation of FcH followed by phosphorylation. The influence of the P-substituents on thermal stability, electrochemical potential, chemical shift, and UV-Vis absorption behavior of the ILs is studied. The phosphonium group acts both as an ionic tag and as an electron-withdrawing substituent directly bound at the Cp-ring position. Therefore the title compounds are attractive for further studies to use them as tunable redox mediators for (photo)electrochemical devices such as dye sensitized solar cells (DSSCs) or redox flow batteries.

SYNTHESIS OF CYTIDINE DIPHOSPHATE-D-QUINOVOSE

The title molecule, cytidine-D-quinovose (CDP-6-deoxy-D-glucose) 1, was synthesized by two different methods from the key intermediate quinovose-1-phosphate 7 which was prepared from glucose.