59592-97-1Relevant academic research and scientific papers
(η5-halogenocyclohexadienyl)Mn(CO)3 complexes: Halogen substitution by arene derivatives
Prim, Damien,Auffrant, Audrey,Rose-Munch, Fran?ois,Rose, Eric,Vaissermann, Jacqueline
, p. 1901 - 1903 (2001)
Unprecedented coupling reactions on (η5-chlorocyclohexadienyl)tricarbonyl manganese complexes with arenes create a new carbon-carbon bond on the conjugated system, keeping intact the η5-chlorocyclohexadienyl moiety; thus, the removal of the exo hydrogen bond of the sp3 CH2 group yields efficiently new cationic (η6-arene) manganese complexes which cannot be prepared directly from the free arene.
Palladium-catalyzed chloride substitution of η5-(Chlorocyclohexadienyl)Mn(CO)3 complexes: An access to novel η6-(Arene)Mn(CO)3+ cations
Auffrant, Audrey,Prim, Damien,Rose-Munch, Francoise,Rose, Eric,Schouteeten, Stephanie,Vaissermann, Jacqueline
, p. 1898 - 1913 (2008/10/08)
Functionalization of η5-(chlorocyclohexadienyl)Mn(CO)3 complexes was achieved by palladium-catalyzed reactions using Pd2(dba)3 in the presence of AsPh3. Arylation, carbonylation, and substitution by a
