Cas 59632-78-9,(((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)oxy)dimethyl(phenyl)silane

59632-78-9

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Basic information

Product Name: (((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)oxy)dimethyl(phenyl)silane
Synonyms: (((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)oxy)dimethyl(phenyl)silane
CAS NO:59632-78-9
Molecular Formula:
Molecular Weight: 290.521
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: (((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)oxy)dimethyl(phenyl)silane(CAS DataBase Reference)
NIST Chemistry Reference: (((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)oxy)dimethyl(phenyl)silane(59632-78-9)
EPA Substance Registry System: (((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)oxy)dimethyl(phenyl)silane(59632-78-9)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 59632-78-9(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 59632-78-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,9,6,3 and 2 respectively; the second part has 2 digits, 7 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 59632-78:
(7*5)+(6*9)+(5*6)+(4*3)+(3*2)+(2*7)+(1*8)=159
159 % 10 = 9
So 59632-78-9 is a valid CAS Registry Number.

59632-78-9Upstream product

59632-78-9Downstream Products

59632-78-9Relevant academic research and scientific papers

Dehydrogenative Silylation of Alcohols Under Pd-Nanoparticle Catalysis

Pramanik, Suman,Fernandes, Anthony,Liautard, Virginie,Pucheault, Mathieu,Robert, Frederic,Landais, Yannick

, p. 728 - 732 (2019)

Pd-nanoparticle-catalyzed dehydrogenative coupling between various hydrosilanes and alcohols was shown to provide silyl ethers in good and reproducible yields. The synthetic methodology is effective for a wide range of simple and bulky silanes and secondary alcohols, while keeping various other functional groups intact. The procedure also exhibits high selectivity for the silylation of primary versus secondary alcohols in 1,2-diols, and allows the successive silylation of alkynols and hydrogenation of the triple bond to afford Z-alkenols in good yields.

Active cobalt catalyst for the cleavage of benzyl ether

Wang, Bo,Yin, Zhaojun,Li, Yangbing,Yang, Ting-Xiang,Meng, Xiang-Bao,Li, Zhong-Jun

experimental part, p. 9531 - 9535 (2012/01/05)

An improved method for the deprotection of benzyl ethers using a catalytic amount of Co2(CO)8 in the presence of Me2PhSiH and CO (1 atm) is described. The deprotection reaction is compatible with double bond or sulfur-cont

Rate enhancement with a bowl-shaped phosphane in the rhodium-catalyzed hydrosilylation of ketones

Niyomura, Osamu,Tokunaga, Makoto,Obora, Yasushi,Iwasawa, Tetsuo,Tsuji, Yasushi

, p. 1287 - 1289 (2007/10/03)

Up to 154-fold rate enhancement (see picture) and higher yields are achieved with the bowl-shaped triarylphosphane ligand P(tm-tp)3 compared with common phosphane ligands in Rh-catalyzed hydrosilylation of ketones. The superior performance of P(tm-tp)3 over the similar P(tp)3 is apparently related to the deeper bowl formed by the methyl-bearing terphenyl substituents in the former.

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