59661-77-7Relevant articles and documents
Electrochemical Oxidation Enables Regioselective and Scalable α-C(sp3)-H Acyloxylation of Sulfides
Wang, Huamin,He, Meng,Li, Yongli,Zhang, Heng,Yang, Dali,Nagasaka, Masanari,Lv, Zongchao,Guan, Zhipeng,Cao, Yangmin,Gong, Fengping,Zhou, Zhilin,Zhu, Jingyun,Samanta, Supravat,Chowdhury, Abhishek Dutta,Lei, Aiwen
supporting information, p. 3628 - 3637 (2021/04/07)
A highly selective, environmentally friendly, and scalable electrochemical protocol for the construction of α-acyloxy sulfides, through the synergistic effect of self-assembly-induced C(sp3)-H/O-H cross-coupling, is reported. It features exceptionally broad substrate scope, high regioselectivity, gram-scale synthesis, construction of complex molecules, and applicability to a variety of nucleophiles. Moreover, the soft X-ray absorption technique and a series of control experiments have been utilized to demonstrate the pivotal role of the self-assembly of the substrates, which indeed is responsible for the excellent compatibility and precise control of high regioselectivity in our electrochemical protocol.
Metal-assisted Reactions. Part 18. Reaction of Titanium Tetrachloride with Cyclic Sulphides: Novel Bicyclic Disulphur Compounds
Delaney, Paul A.,Johnstone, Robert A. W.,Boehm, Peter,Entwistle, Ian D.
, p. 1861 - 1864 (2007/10/02)
In marked contrast to the reaction of tetrahydrofuran with TiCl4, tetrahydrothiophene did not afford ring-opened products.Instead, small quantities of ring-dimers were produced, possibly via initial chlorination and dehydrochlorination to produce 2,3-dihy
