596805-82-2Relevant academic research and scientific papers
Highly enantioselective hetero-Diels-Alder reactions between Rawal's diene and aldehydes catalyzed by chiral dirhodium(ii) carboxamidates
Watanabe, Yudai,Washio, Takuya,Shimada, Naoyuki,Anada, Masahiro,Hashimoto, Shunichi
, p. 7294 - 7296 (2009)
The first example of a chiral Lewis acid-catalyzed enantioselective hetero-Diels-Alder (HDA) reaction between 1-dimethylamino-3-silyloxy-1,3- butadiene (Rawal's diene) and aldehydes is described. The cycloaddition reaction under the influence of 1 mol% of
