59691-19-9Relevant academic research and scientific papers
Non-Cryogenic, Ammonia-Free Reduction of Aryl Compounds
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, (2022/03/31)
A method of reducing an aromatic ring or a cyclic, allylic ether in a compound includes preparing a reaction mixture including a compound including an aromatic moiety or a cyclic, allylic ether moiety, an alkali metal, and either ethylenediamine, diethylenetriamine, triethylenetetramine, or a combination thereof, in an ether solvent; and reacting the reaction mixture at from ?20° C. to 30° C. for a time sufficient to reduce a double bond in the aromatic moiety to a single bond or to reduce the cyclic, allylic ether moiety.
Novel electronic salt system and method for reducing unsaturated hydrocarbon compound
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Paragraph 0188-0192, (2018/09/08)
The invention discloses an electronic salt system and a method for reducing unsaturated hydrocarbon compounds by using the electronic salt system, belongs to the field of organic synthesis, and solvesthe problems such as complicated operation, harsh conditions, easy generation of complex over-reduction products of methods for reducing the unsaturated hydrocarbon compounds in the prior art. An electron salt may be synthesized by an alkali metal reagent, an ether and an alcohol, the ether can be a crown ether or a cryptand; and the method adopts the electronic salt system, the unsaturated hydrocarbon compounds is reduced by the electronic salt system in an organic solvent. The method for reducing the unsaturated hydrocarbon compounds is used for reducing the unsaturated hydrocarbon compounds.
Synthesis of trans-perhydroisoquinolines by 6-endo-trig radical cyclization of amino-tethered vinyl bromides and cyclohexenes
Quirante, Josefina,Vila, Xavier,Paloma, Laura,Guiu, Josep M.,Bonjoch, Josep
, p. 1372 - 1379 (2007/10/03)
Bu3SnH-promoted cyclization of several N-(2-bromoprop-2-enyl)-N-[(4-oxocyclohex-1-enyl)methyl]alkylamines is reported. It has been found that the generated vinyl radicals evolve through a 6-endo-cyclization pathway giving rise to the correspond
Enantioselective total synthesis of the antifungal natural products chorotetaine, bacilysin, and anticapsin and of related compounds: Revision of the relative configuration
Wild
, p. 2748 - 2761 (2007/10/02)
Enantioselective and diastereoselective syntheses of the title antifungal natural products and some of their diastereoisomers are described. Key steps include the diastereoselective 1,6-addition of bislactim ether 14 and a stereoselective deprotonation of
