59693-90-2

Basic information

• Product Name: n-hexyl 4-methoxyphenyl sulfide
• Synonyms: n-hexyl 4-methoxyphenyl sulfide
• CAS NO: 59693-90-2
• Molecular Weight: 224.367
• Mol File: 59693-90-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: n-hexyl 4-methoxyphenyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: n-hexyl 4-methoxyphenyl sulfide(59693-90-2)
• EPA Substance Registry System: n-hexyl 4-methoxyphenyl sulfide(59693-90-2)

Safety Data

• Hazardous Substances Data: 59693-90-2(Hazardous Substances Data)

Upstream product

• 696-63-9 4-Methoxybenzenethiol 
• 111-25-1 1-bromo-hexane 
• 111-31-9 Hexanethiol 
• 100-66-3 methoxybenzene 
• 696-62-8 para-iodoanisole 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 2307-12-2 S-hexyl ethanethioate 
• 22487-02-1 sodium n-hexylmercaptide 

Downstream Products

• 13349-96-7 4-(hexylthio)phenol 

Relevant articles and documents

Direct C-H Thiolation for Selective Cross-Coupling of Arenes with Thiophenols via Aerobic Visible-Light Catalysis

An aerobic metal-free, visible-light-induced regioselective thiolation of phenols with thiophenols is reported. The cross-coupling protocol exhibits great functional group tolerance and high regioselectivity. Mechanistic studies reveal that the disulfide

A general rhodium-catalyzed cross-coupling reaction of thiols with aryl iodides

The general procedure for the rhodium-catalyzed cross-coupling of thiols with aryl iodides is described. The catalytic system consists of 5 mol % of [RhCl(cod)]2 and 10 mol % of PPh3 as a ligand. A variety of aryl iodides reacted with thiols, giving aryl thioethers in good to excellent yields. It is important to note that the deactivated aryl iodides such as 4-iodoanisole is worked smoothly to provide the corresponding aryl thioethers in excellent yields. Functional groups such as free-amines, chloro, are all tolerated under the employed reaction conditions.

Alkyl- and Arylthiodediazoniations of Dry Arenediazonium o-Benzenedisulfonimides. Efficient and Safe Modifications of the Stadler and Ziegler Reactions to Prepare Alkyl Aryl and Diaryl Sulfides

The reaction between dry arenediazonium o-benzenedisulfonimides 1 and sodium thiolates in anhydrous methanol represents an efficient and safe procedure, of general validity, for the preparation of unfunctionalized or variously functionalized alkyl aryl and diaryl sulfides. As a rule, the reaction temperature was maintained at 0-5°C for the alkylthiodediazoniations and at room temperature (20-25°C) for the arylthiodediazoniations. The sulfide yields are generally high; of the 63 considered examples, 43 gave yields greater than 80% and 13 were between 70% and 80%. Lower yields were obtained only when sterically hindered diazonium salts or thiols were used. A good amount of the o-benzenedisulfonimide (8) was always recovered from the reactions and could be reused to prepare salts 1. The copious experimental data collected in homogeneous conditions have offered several starting points for the study of the mechanism of these reactions.