59696-36-5Relevant academic research and scientific papers
Alternative Strategies with Iodine: Fast Access to Previously Inaccessible Iodine(III) Compounds
Hokamp, Tobias,Mollari, Leonardo,Wilkins, Lewis C.,Melen, Rebecca L.,Wirth, Thomas
supporting information, p. 8306 - 8309 (2018/06/29)
Non-iodinated arenes can be easily and selectively converted into (diacetoxyiodo)arenes in a single step under mild conditions by using iodine triacetates as reagents. The oxidative step is decoupled from the synthesis of hypervalent iodine(III) reagents, which can now be prepared conveniently in a one-pot synthesis for subsequent reactions without prior purification. The chemistry of iodine triacetates was also expanded to heteroatom ligand exchanges to form novel inorganic hypervalent iodine compounds.
Easy and safe preparations of (diacetoxyiodo)arenes from iodoarenes, with Urea-Hydrogen Peroxide adduct (UHP) as the oxidant and the fully interpreted 1H- and 13C-NMR spectra of the products
Zielinska, Agnieszka,Skulski, Lech
, p. 190 - 194 (2007/10/03)
An easy and safe, though only moderately effective method is presented for preparing (diacetoxyiodo)arenes, ArI(OAc)2, from iodoarenes, ArI, using the commercially available and easily handled urea-hydrogen peroxide adduct (UHP) as the oxidant. The reactions take place in anhydrous AcOH/Ac2O/AcONa (a catalyst) mixtures, at 40°C for 3.5 h to afford the purified ArI(OAc)2 in 37-78% yields. The fully interpreted 1H- and 13C-NMR spectra of the ArI(OAc)2 products are reported.
FURTHER FUNCTIONAL GROUP OXIDATIONS USING SODIUM PERBORATE
McKillop, Alexander,Kemp, Duncan
, p. 3299 - 3306 (2007/10/02)
Sodium perborate in acetic acid is an effective reagent for the oxidation of aromatic aldehydes to carboxylic acids, iodoarenes to (diacetoxyiodo)arenes, azines to N-oxides, and various types of sulfur heterocycles to S,S-dioxides.Nitriles are unaffected by the reagent in acetic acid, but undergo smooth hydration to amides when aqueous methanol is employed as solvent.
